210633-64-0Relevant academic research and scientific papers
From toluene to taxol: Chemoenzymatic and enantiodivergent routes to the AB-ring systems of taxoids and ent-taxoids
Banwell, Martin G.,Darmos, Penny,McLeod, Malcolm D.,Hockless, David C. R.
, p. 897 - 899 (1998)
The cis-1,2-dihydrocatechol 2 has been converted, via reaction sequences including Diels-Alder cycloaddition and anionic oxy-Cope rearrangement steps, into the enantiopure bicyclo[5.3.1]undecanes 20 and 33 which correspond to the AB-ring systems of ent-ta
The enantiocontrolled synthesis of a highly functionalized cyclohexenone related to the A-ring of the furanosteroid viridin
Findlay, Alison D.,Gebert, Antje,Cade, Ian A.,Banwell, Martin G.
scheme or table, p. 1173 - 1180 (2010/03/01)
A seven-step reaction sequence has been used to convert the enantiomerically pure cis-1,2-dihydrocatechol 10 into the cyclohexenone 17a. A near equivalent sequence involving the same starting material has allowed for the synthesis of the regioisomeric sys
Taxane diterpene synthesis studies. Part 2: Towards taxinine - enantiospecific construction of an AB-ring substructure incorporating both quaternary carbon centres and attempts to annulate the C-ring
Banwell, Martin G.,McLeod, Malcolm D.,Riches, Andrew G.
, p. 53 - 66 (2007/10/03)
In connection with efforts to develop an efficient total synthesis of the biologically active natural product taxinine 1, the enzymatically-derived and monochiral cis-1,2-dihydrocatechol 7 was converted, over several steps including a Diels-Alder cycloadd
