210633-68-4Relevant academic research and scientific papers
Taxane diterpene synthesis studies. Part 2: Towards taxinine - enantiospecific construction of an AB-ring substructure incorporating both quaternary carbon centres and attempts to annulate the C-ring
Banwell, Martin G.,McLeod, Malcolm D.,Riches, Andrew G.
, p. 53 - 66 (2007/10/03)
In connection with efforts to develop an efficient total synthesis of the biologically active natural product taxinine 1, the enzymatically-derived and monochiral cis-1,2-dihydrocatechol 7 was converted, over several steps including a Diels-Alder cycloadd
From toluene to taxol: Chemoenzymatic and enantiodivergent routes to the AB-ring systems of taxoids and ent-taxoids
Banwell, Martin G.,Darmos, Penny,McLeod, Malcolm D.,Hockless, David C. R.
, p. 897 - 899 (2007/10/03)
The cis-1,2-dihydrocatechol 2 has been converted, via reaction sequences including Diels-Alder cycloaddition and anionic oxy-Cope rearrangement steps, into the enantiopure bicyclo[5.3.1]undecanes 20 and 33 which correspond to the AB-ring systems of ent-ta
