210708-43-3Relevant academic research and scientific papers
First diastereoselective asymmetric carbometallation of chiral vinyl metals
Brasseur, Denis,Rezaei, Hadi,Fuxa, Alain,Alexakis, Alexandre,Mangeney, Pierre,Marek, Ilan,Normant, Jean F.
, p. 4821 - 4824 (1998)
Addition of substituted allylzinc reagents to chiral (Z) metallated allyl amines (or aminal) bearing a chiral aromatic moiety is face selective, and delivers β-methylated amines with good diastereomeric excess.
