First diastereoselective asymmetric carbometallation of chiral vinyl metals

DOI: 10.1016/S0040-4039(98)00942-3

Source and publish data:

Tetrahedron Letters p. 4821 - 4824 (1998)

Update date:2022-08-05

Topics:

Authors:

Brasseur, Denis

Rezaei, Hadi

Fuxa, Alain

Alexakis, Alexandre

Mangeney, Pierre

Marek, Ilan

Normant, Jean F.

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Article abstract of DOI:10.1016/S0040-4039(98)00942-3

Addition of substituted allylzinc reagents to chiral (Z) metallated allyl amines (or aminal) bearing a chiral aromatic moiety is face selective, and delivers β-methylated amines with good diastereomeric excess.

Full text of DOI:10.1016/S0040-4039(98)00942-3

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Product name:((Z)-3-Iodo-allyl)-methyl-((S)-1-phenyl-ethyl)-amine

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