First diastereoselective asymmetric carbometallation of chiral vinyl metals

DOI: 10.1016/S0040-4039(98)00942-3

Source and publish data:

Tetrahedron Letters p. 4821 - 4824 (1998)

Update date:2022-08-05

Topics:

Authors:

Brasseur, Denis

Rezaei, Hadi

Fuxa, Alain

Alexakis, Alexandre

Mangeney, Pierre

Marek, Ilan

Normant, Jean F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00942-3

Addition of substituted allylzinc reagents to chiral (Z) metallated allyl amines (or aminal) bearing a chiral aromatic moiety is face selective, and delivers β-methylated amines with good diastereomeric excess.

Full text of DOI:10.1016/S0040-4039(98)00942-3

Products guided by the article

Product name:((Z)-3-Iodo-allyl)-methyl-((S)-1-phenyl-ethyl)-amine

Cas No:210708-43-3

R&D Labs maybe for 210708-43-3

Evershine Chemical CO Ltd

Contact:+86-571-87010026

Address:202, Zhenhua Road,
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China

Relevant to this article

Design, synthesis, and biological activities of potent and selective somatostatin analogues incorporating novel peptoid residues

Doi:10.1021/jm970393l
(1998)
Synthesis of novel polyazadipyridinocyclophane scaffolds and their application for the generation of libraries

Doi:10.1016/S0040-4020(98)00441-4
(1998)
The selective C-mono-and C,C-dialkylation of thiophosphorylacetonitriles and reactivity of the products

Doi:10.1080/10426509908546313
(1999)
Seven-coordinate thiophene-3-acetonitrile complexes of tungsten(II). Crystal structures of [WI₂(CO)₃{NCCH₂(3-C₄H₃S)} ₂] and [WI₂(CO)₃{NCCH₂(3-C₄H₃S)} (AsPh₃)]

Doi:10.1016/S0022-328X(98)00491-4
(1998)
Bis[N-(2-bromo-4-methylphenyl)-naphthaldiminato]copper(II)

Doi:10.1107/S0108270198003345
(1998)
Chloroacridine derivatives as potential anticancer agents which may act as tricarboxylic acid cycle enzyme inhibitors

Doi:10.1016/j.biopha.2020.110515
(2020)

Article Doi