210817-72-4

Basic information

• Product Name: trans-[Os(II)(2,2':6',2''-terpyridine)(Cl)2(NCC₆H₅)]
• CAS NO: 210817-72-4
• Molecular Weight: 597.502
• Mol File: 210817-72-4.mol

Chemical Properties

• CAS DataBase Reference: trans-[Os(II)(2,2':6',2''-terpyridine)(Cl)2(NCC₆H₅)](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[Os(II)(2,2':6',2''-terpyridine)(Cl)2(NCC₆H₅)](210817-72-4)
• EPA Substance Registry System: trans-[Os(II)(2,2':6',2''-terpyridine)(Cl)2(NCC₆H₅)](210817-72-4)

Safety Data

• Hazardous Substances Data: 210817-72-4(Hazardous Substances Data)

Upstream product

• 127571-48-6 {Os(N)(2,2':6',2''-terpyridine)Cl₂} hexafluorophosphate 
• 100-47-0 benzonitrile 
• 38011-36-8 bis(triphenylphosphorylidene)ammonium azide 
• 1184-78-7 trimethylamine-N-oxide 
• 250655-35-7 cis-[(terpy)OsCl2(1,2-η(2)-PhCHNCHPh)]PF6 

Relevant articles and documents

Reactivity of Osmium(VI) Nitrides with the Azide Ion. A New Synthetic Route to Osmium(II) Polypyridyl Complexes

There is an extensive reactivity chemistry between trans-[OsVI(tpy)(Cl)2(N)]+ (1) (tpy = 2.2′:6′,2″-terpyridine) and N3-. Reaction of 1 with N3- in CH2C12 or acetone occurs by electron transfer to give trans,trans-(tpy)(Cl)2OsII(N2)Os II(Cl)2(tpy). In CH3CN, trans-OsII(tpy)(Cl)2(N2) forms but undergoes solvolysis to give transOsII(tpy)(Cl)2(CH3CN). 1 reacts with excess N3- in CH3CN to give OsIII(tpy)(Cl)2(5-CH3-tetrazolate), which has been characterized by X-ray crystallography. This is the first known Os-tetrazolato complex. 1 reacts with N3- in the presence of CS2 to give trans-[OsII(tpy)(Cl)2(NS)]+, SCN-, and N2.