210840-41-8Relevant academic research and scientific papers
Oxidation-induced Acyl group transfer from hydroquinone esters to nucleophiles
Reischl, Gerald,El-Mobayed, Medhat,Bei?wenger, Rudolf,Regier, Klaus,Maichle-M?ssmer, C?cilia,Rieker, Anton
, p. 765 - 773 (1998)
Bivalent oxidation of 3,5-di-tert-butyl-hydroquinone monoesters leads to phenoxenium ions, which can transfer an acyl group to nucleophiles. Based on this principle, dipeptides, glyco-amino acids and N-sulfonyl-amino acids were synthesized from hydroquino
SYNTHESES VIA ANODICALLY PRODUCED PHENOXENIUM IONS. APPLICATIONS IN THE FIELD OF PEPTIDES AND CARBOHYDRATES
Rieker, Anton,Beisswenger, Rudolf,Regier, Klaus
, p. 645 - 654 (2007/10/02)
Sterically hindered phenols are anodically oxidized to the corresponding phenoxenium ions which react with O- and N-nucleophiles to give cyclohexadienyl-protected nucleophiles. 4-Acyloxy substituted phenoxenium ions can transfer the acyl group to nucleoph
