21086-47-5Relevant academic research and scientific papers
Copper-catalyzed electrosynthesis of 1-acyl-2,2-diphenylcyclopropanes and their behaviour in acidic medium
Oudeyer, Sylvain,Léonel, Eric,Paugam, Jean Paul,Nédélec, Jean-Yves
, p. 1073 - 1081 (2003)
The formation of 1-acyl-2,2-diphenylcyclopropanes is performed under mild electrochemical conditions. These cyclopropane derivatives, through acid-catalyzed ring-opening, lead to γ,γ-diphenyl-β,γ-unsaturated carbonyl compounds which evolve into either substituted naphthalenes, or β-benzhydryl-α,β-cycloalkenones depending on the acyclic or cyclic nature of the intermediate allyl ketone.
Regioselective arylation on the γ-position of α, β-unsaturated carbonyl compounds with aryl bromides by palladium catalysis
Terao, Yoshito,Satoh, Tetsuya,Miura, Masahiro,Nomura, Masakatsu
, p. 6203 - 6206 (2007/10/03)
Arylation of 2-substituted 2-alkenals and 3-substituted 2-cyclohexen- and 2-cyclopenten-1-ones can effectively and regioselectively proceed at their γ-position by treatment with aryl bromides in the presence of a palladium catalyst and a base.
