21086-38-4Relevant academic research and scientific papers
Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis
Petronijevic, Filip R.,Nappi, Manuel,MacMillan, David W. C.
supporting information, p. 18323 - 18326 (2014/01/06)
The direct β-coupling of cyclic ketones with aryl ketones has been achieved via the synergistic combination of photoredox catalysis and organocatalysis. Diaryl oxymethyl or aryl-alkyl oxymethyl radicals, transiently generated via single-electron reduction
BIS(TRI-n-BUTYLSTANNYL)BENZOPINACOLATE: PREPARATION AND USE AS A MEDIATOR OF INTERMOLECULAR FREE RADICAL REACTIONS
Hart, David J.,Krishnamurthy, Ramanarayanan,Pook, Lori M.,Seely, Franklin L.
, p. 7819 - 7822 (2007/10/02)
Bis(tri-n-butylstannyl)benzopinacolinate (2) serves as a thermal source of tri-n-butylstannyl radicals and mediates intermolecular coupling of selected alkyl halides to O-benzylformaldoxime and electron deficient olefins.A free radical non-chain mechanism is proposed for these reactions.
Ytterbium Metal Mediated Synthesis of Symmetrical and Unsymmetrical Pinacols from Carbonyl Compounds
Hou, Zhaomin,Takamine, Kan,Fujiwara, Yuzo,Taniguchi, Hiroshi
, p. 2061 - 2064 (2007/10/02)
Reaction of aromatic aldehydes and ketones with ytterbium metal gives the corresponding pinacols in high yields.Cross-coupling reaction of benzophenone with other carbonyl compounds to produce unsymmetrical pinacols is also described.
