211386-13-9Relevant academic research and scientific papers
[3 + 2] annulation of β-heteroatom-substituted α,β-unsaturated acylsilanes with methyl ketone enolates: Scope and investigation of the reaction course
Takeda, Kei,Yamawaki, Kenji,Hatakeyama, Noriaki
, p. 1786 - 1794 (2007/10/03)
A new route to (Z)-β-silylacryloylsilanes 10 and the improved conditions for the [3 + 2] annulation using 10 and alkyl methyl ketone enolates are reported. Also, details of investigations defining a reaction course of the [3 + 2] annulation using β-phenylthio- and β-trimethylsilyl-acryloylsilanes 1 (X = SPh, SiMe3) and alkyl methyl ketone enolates are described.
Comparing α-carbanion-stabilizing ability of substituents using the Brook rearrangement
Takeda, Kei,Ubayama, Haruka,Sano, Ayako,Yoshii, Eiichi,Koizumi, Toru
, p. 5243 - 5246 (2007/10/03)
The α-carbanion-stabilizing ability of the phenylthio and trimethylsilyl groups was compared based on the relative rate of the base- catalyzed Brook rearrangement of the β-substituted α-silylallylalcohol.
