211565-42-3Relevant academic research and scientific papers
PHOSPHOROAMIDE COMPOUND, METHOD FOR PRODUCING THE SAME, LIGAND, COMPLEX, CATALYST, AND METHOD FOR PRODUCING OPTICALLY ACTIVE ALCOHOL
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Page/Page column 27, (2009/12/23)
Disclosed is a method for highly efficiently obtaining an optically active alcohol from a carbonyl compound highly enantioselectively. Also disclosed is a ligand used in such a method. Specifically, an optically active alcohol is obtained by reacting a ca
The use of phosphinamide N-protecting groups in the diastereoselective reduction of ketones
Palmer, Matthew J.,Studley, John R.,Walsgrove, Tim C.,Wills, Martin
, p. 8827 - 8840 (2007/10/03)
The phosphinamide N-protecting group is demonstrated to be an effective directing group for diastereoselective reductions of proximal ketones. A range of methods for the preparation of the requisite α-amino ketones substrates are described.
