211869-58-8

Basic information

• Product Name: (1S,2R)-2-(4-vinylbenzenesulfonyl)amino-1-phenylpropan-1-ol
• Synonyms: (1S,2R)-2-(4-vinylbenzenesulfonyl)amino-1-phenylpropan-1-ol
• CAS NO: 211869-58-8
• Molecular Weight: 317.409
• Mol File: 211869-58-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R)-2-(4-vinylbenzenesulfonyl)amino-1-phenylpropan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R)-2-(4-vinylbenzenesulfonyl)amino-1-phenylpropan-1-ol(211869-58-8)
• EPA Substance Registry System: (1S,2R)-2-(4-vinylbenzenesulfonyl)amino-1-phenylpropan-1-ol(211869-58-8)

Safety Data

• Hazardous Substances Data: 211869-58-8(Hazardous Substances Data)

Upstream product

• 2633-67-2 4-vinylbenzenesulfonyl chloride 
• 37577-28-9 (1S,2R)-(+)-norphedrine 

Relevant articles and documents

Enantioselective Synthesis of Chiral Homoallyl Alcohols and Homoallylamines by Nucleophilic Addition of an Allylboron Reagent Modified by a Polymer-Supported Chiral Ligand

Crosslinked polymer-supported chiral N-sulfonylamino alcohols 5-8 have been prepared by suspension polymerization of enantiopure N-sulfonylamino alcohol monomers 1-4 with styrene and divinylbenzene. Polymer-supported chiral allylboron reagents were prepared from the polymeric chiral ligands. Enantioselective additions of the polymer-supported allylboron reagents to aldehydes and N-(trimethylsilyl)imines have been successfully carried out in the heterogeneous system. The corresponding optically active homoallyl alcohols and homoallylamines were obtained in high yields with high enantioselectivities (up to 95% ee) which are almost the same as those obtained from homogeneous analogues. The polymer-supported chiral ligands used were recovered easily and can be reused without any loss of activity.