2633-67-2Relevant articles and documents
Enantioselective addition of organozinc reagents to ketones catalyzed by grafted isoborneolsulfonamide polymers and titanium isopropoxide
Forrat, Vicente J.,Ramon, Diego J.,Yus, Miguel
, p. 65 - 67 (2009)
The catalytic enantioselective addition of different organozinc reagents, such as diethylzinc, or in situ generated phenylzinc derivatives to simple aryl methyl ketones was accomplished using titanium tetraisopropoxide and a polymeric ligand grafted with
Influence of Chain Rigidity and Dielectric Constant on the Glass Transition Temperature in Polymerized Ionic Liquids
Bocharova,Wojnarowska,Cao, Peng-Fei,Fu,Kumar,Li, Bingrui,Novikov,Zhao,Kisliuk,Saito,Mays, Jimmy W.,Sumpter,Sokolov
, p. 11511 - 11519 (2017)
Polymerized ionic liquids (PolyILs) are promising candidates for a wide range of technological applications due to their single ion conductivity and good mechanical properties. Tuning the glass transition temperature (Tg) in these materials con
Molded, high surface area polymer electrolyte membranes from cured liquid precursors
Zhou, Zhilian,Dominey, Raymond N.,Rolland, Jason P.,Maynor, Benjamin W.,Pandya, Ashish A.,DeSimone, Joseph M.
, p. 12963 - 12972 (2006)
Polymer electrolyte membranes (PEMs) for fuel cells have been synthesized from easily processable, 100% curable, low molecular weight reactive liquid precursors that are photochemically cured into highly proton conductive solid membranes. The liquid precu
Synthesis, Characterization, and Biological Investigation of Alanine-Based Sulfonamide Derivative: FT-IR, 1H NMR Spectra: MEP, HOMO–LUMO Analysis, and Molecular Docking
Parvaneh Shafieyoon,Mehdipour, Ebrahim,Michalski, Jacek
, p. 1285 - 1296 (2019)
Abstract: A combined experimental and theoretical investigation has been reported on N-(alanine)-p-styrene sulfonamide (abbreviated as ASS). The new title compound have been synthesized for the first time from the reaction of p-styrene sulfonyl chloride a
Latent reactive groups unveiled through equilibrium dynamics and exemplified in crosslinking during film formation from aqueous polymer colloids
Berrisford, David J.,Lovell, Peter A.,Suliman, Nadia R.,Whiting, Andrew
, p. 5904 - 5906 (2005)
The concept of using equilibrium dynamics to provide for both protection and unveiling of latent functional groups at appropriate times in aqueous polymer colloid coatings designed for crosslinking only during film formation is introduced; the new functional monomer, 4-hydroxyethylsulfonylstyrene (HESS), readily undergoes emulsion copolymerization with acrylates to form stable latexes, followed by crosslinking by loss of water during film formation. The Royal Society of Chemistry 2005.
Realisation of ORMOSIL ionomers by the crosslinking of propyl methacrylate siloxane and a protected styrenesulfonic acid
Apperley, David C.,Evans, Philip J.,Slade, Robert C. T.,Varcoe, John R.,Young, Kevin E.
, p. 849 - 858 (2000)
1,2,3,4-Tetrahydro-1-naphthylideneamino styrene-p-sulfonate (NISS) and poly(propyl methacrylate siloxane) (PMS) were free-radically crosslinked, yielding insoluble copolymers in which the siloxane and NISS components appear well intermixed. These material
NEW POLYMERS AND THE USE THEREOF FOR DETECTING ION FLUXES
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, (2022/03/02)
Disclosed are ion-sensitive polymers and methods for their use for monitoring biological phenomena associated with ion fluxes, as well as organic electrochemical transistors including such polymers.
Method of manufacturing a polymerizable functional group having a sulfonimide salts
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Paragraph 0048-0050, (2021/11/27)
[Problem] high-sulfonimide acids without passing through self-polymerization, to cause halogen residual amine salt as a raw material without using a radiosensitive, simple, high yield, high purity industrial scale production method of adsorbing silver hal
Scalable and Recyclable All-Organic Colloidal Cascade Catalysts
Chen, Chen,Gr?schel, André H.,Gramse, Christian,Janoszka, Nicole,Weberskirch, Ralf,Wong, Chin Ken
supporting information, p. 237 - 241 (2020/10/30)
We report on the synthesis of core–shell microparticles (CSMs) with an acid catalyst in the core and a base catalyst in the shell by surfactant-free emulsion polymerization (SFEP). The organocatalytic monomers were separately copolymerized in three synthetic steps allowing the spatial separation of incompatible acid and base catalysts within the CSMs. Importantly, a protected and thermo-decomposable sulfonate monomer was used as acid source to circumvent the neutralization of the base catalyst during shell formation, which was key to obtain stable, catalytically active CSMs. The catalysts showed excellent performance in an established one-pot model cascade reaction in various solvents (including water), which involved an acid-catalyzed deacetalization followed by a base-catalyzed Knoevenagel condensation. The CSMs are easily recycled, modified, and their synthesis is scalable, making them promising candidates for organocatalytic applications.
Highly selective electroreductive linear dimerization of electron-deficient vinylarenes
Ning, Shulin,Zheng, Lianyou,Bai, Ya,Wang, Shutao,Wang, Siyu,Shi, Lingling,Gao, Qiansong,Che, Xin,Zhang, Zhuoqi,Xiang, Jinbao
supporting information, (2021/11/16)
A direct electroreductive dimerization of electron-deficient vinylarenes for the synthesis of 1,4-diarylbutane has been developed using a simple undivided cell with inexpensive carbon electrodes at room temperature. The control and deuterium-labeling experiments of electroreductive dimerization suggest that the hydrogen source comes from the solvent CH3CN. This protocol provides a mild and efficient route for the construction of C–C bond in moderate to good yields with high regioselectivity and broad substrate scope.