211931-26-9

Basic information

• Product Name: (1R,2R,3R,4S,S_S)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane
• Synonyms: (1R,2R,3R,4S,S_S)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane
• CAS NO: 211931-26-9
• Molecular Weight: 342.459
• Mol File: 211931-26-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,2R,3R,4S,S_S)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,3R,4S,S_S)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane(211931-26-9)
• EPA Substance Registry System: (1R,2R,3R,4S,S_S)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>heptane(211931-26-9)

Safety Data

• Hazardous Substances Data: 211931-26-9(Hazardous Substances Data)

Upstream product

• 211931-21-4 (1R/1S,S_S)-1-<3-(p-tolylsulfinyl)-2-furyl>-trans-crotyl alcohol 
• 177547-57-8 (S_S)-2-trans-crotonyl-3-(p-tolylsulfinyl)furan 
• 143810-75-7 (+)-(SS)-3-(p-tolylsulfinyl)furan 
• 177547-59-0 (1S,2S,3R,4R,S_S)-2-<3-(p-tolylsulfinyl)-2-furoyl>-3-methylbicyclo<2.2.1>hept-5-ene 

Relevant articles and documents

Remote asymmetric induction in lewis acid-catalyzed Diels-Alder reaction of α,β-unsaturated enones having a chiral sulfinyl-substituted, 5-membered aromatic heterocycle

Two types of chiral sulfoxides as Diels-Alder dienophiles were synthesized and high levels of diastereoselectivity were observed in cycloadditions. 2-Furyl and 2-thienyl α,β-enones, bearing a chiral sulfinyl group in the heterocycle, served as efficient dienophiles in Diels-Alder reactions, where the catalytic use of aluminium chloride or a lanthanide triflate effected the cycloaddition with cyclopentadiene affording the endo adduct with high diastereoselectivity, ranging from 91% to 98%.