212051-67-7

Basic information

• Product Name: [RuH(η(6)-p-cymene)(AsPh3)2]PF6
• CAS NO: 212051-67-7
• Molecular Weight: 993.741
• Mol File: 212051-67-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuH(η(6)-p-cymene)(AsPh3)2]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: [RuH(η(6)-p-cymene)(AsPh3)2]PF6(212051-67-7)
• EPA Substance Registry System: [RuH(η(6)-p-cymene)(AsPh3)2]PF6(212051-67-7)

Safety Data

• Hazardous Substances Data: 212051-67-7(Hazardous Substances Data)

Upstream product

• 26042-63-7 silver(I) hexafluorophosphate 
• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 603-32-7 triphenyl-arsane 

Relevant articles and documents

Synthesis and characterization of some arene hydrido-complexes 6-arene)(EPh3)2H>+ (η6-arene = benzene, p-cymene or hexamethylbenzene; E = P, As or Sb). Crystal structure of 6-C6H6)(PPh3)2H>BF4

6-arene)Cl2)2> (η6-arene = benzene, p-cymene or hexamethylbenzene) reacts with EPh3 (E = P, As or Sb) in methanol to give monomeric cationic arene hydrido complexes 6-arene)(EPh3)2H>+ in presence of AgBF4 or AgPF6.However, reactions in presence of triphenylphosphine also yield a symmetrically bridged tris (μ-methoxy) complex +.The crystal structure of 6-C6H6)(PPh3)2H>BF4 has been determined.Crystal data, monoclinic system, space group P21/n, a=14.792 (2) Angstroem; b=14.351 (1) Angstroem; c=17.661 (2) Angstroem; β=102.25 (1) deg and Z=4.Crystal structure determination reveals the distortion of the Ru(PPh3)2H+ unit in the cation 6-C6H6)(PPh3)2H>+. - Keywords: Arene hydrido complexes; Ruthenium; Phosphine; Arsine; Stibine