21209-82-5

Upstream product

• 20790-88-9 IrHCl₂(CO)(P(CH₃)2C₆H₅)2 
• 124-41-4 sodium methylate 
• 73191-02-3 (tetrabutylammonium)[IrCl₂(CO)2] 
• 672-66-2 Dimethyl(phenyl)phosphine 
• 112173-03-2 (C₅H₅)FeIrCl(CO)2(P(CH₃)2(C₆H₅))2(CO)(CF₂)⁽¹⁺⁾*BF₄^(1-)={(C₅H₅)FeIrCl(CO)2(P(CH₃)2(C₆H₅))2(CO)(CF₂)}BF₄ 

Downstream Products

• 17595-26-5 IrHCl₂(CO)(P(CH₃)2(C₆H₅))2 
• 77059-30-4 [IrCl₃(CO)(P(CH₃)2C₆H₅)2] 
• 36713-96-9 trans-carbonylchlorobis(dimethylphenylphosphine)rhodium 
• 77018-07-6 [IrCl₃(CO)(P(C₂H₅)2C₆H₅)(P(CH₃)2C₆H₅)] 
• 77018-06-5 trans-[IrCl(CO)(PEt₂Ph)(PMe₂Ph)] 
• 15842-03-2 trans-IrCl(CO){PC₆H₅(C₂H₅)2} 
• 20792-55-6 IrClBr(CO)(P(CH₃)2C₆H₅)2(CH₂CHCH₂) 
• 23319-79-1 IrClBr(CO)(P(CH₃)2C₆H₅)2(CH₂CHCH₂) 
• 23272-82-4 2-methylallylcarbonyldichlorobis(dimethylphenylphosphine)iridium(III) 
• 20756-25-6 allylcarbonyldichlorobis(dimethylphenylphosphine)iridium(III) 
• 71202-40-9 3-methylallylcarbonyldichlorobis(dimethylphenylphosphine)iridium(III) 
• 71202-40-9 IrCl₂(CO)(P(CH₃)2C₆H₅)2(CH(CH₃)CHCH₂) 
• 23318-61-8 IrCl₂(CO)(P(CH₃)2C₆H₅)2C₃H₄Cl 
• 91491-95-1 {Ir(B₄H₉)(CO){P(CH₃)2C₆H₅}2} 

Relevant academic research and scientific papers

A high-yield synthetic approach to trans-[Ir(ER3)2(CO)X] (ER3=PMe3, PEt3, PPhMe2, PPh2Me, P(OMe)3, AsMe3, AsEt3, AsPh3, SbPh3; X=Cl, Br)

The complex [Ir(CO)2X2][NBu4] (X=Cl, Br) forms Vaska-type complexes, trans-[Ir(ER3)2(CO)X], when treated with two equivalents of aryl- or alkyl-phosphines, arsines, or stibines under a CO atmosphere. The synthesis is general for a wide range of phosphines, arsines, or stibines irrespective of the cone angle. For small cone-angle ligands, the initial addition of ligand to [Ir(CO)2X2][NBu4] is performed at low temperature. The synthesis and characterisation of three new Vaska-type complexes trans-[Ir(P(OMe)3)2(CO)Cl], trans-[Ir(AsMe3)2(CO)Cl], and trans-[Ir(AsEt3)2(CO)Cl] is also reported. Elsevier Science Ltd.

Synthesis, structure, and reactivity of a bridging difluorocarbene complex, [CpFeIr(Cl)(CO)2(PMe2Ph)2(μ-CO)(μ-CF 2)][BF4]·CH2Cl2

A heterobimetallic complex with a CF2 bridge, [CpFeIr(CO)2(PMe2Ph)2(μ-CO)(μ-CF 2)][BF4] (1a), was prepared by the oxidative addition of [CpFe(CO)2(CF2)]+ to Ir(Cl)(CO)(PMe2Ph)2. The [BPh4]- salt of the dimetal compound 1a undergoes a Lewis acid displacement with BCl3 to generate the BCl3 adduct of Ir(Cl)(CO)(PMe2Ph)2 and [CpFe(CO)2(CF2)][BPh4]. The crystal structure of 1a reveals a nearly symmetric CF2 bridge between Fe and Ir, whereas a CO ligand is in a semibridging position between these two metal atoms. Crystal data: monoclinic, space group P21/n, a = 9.308 (2) A?, b = 16.447 (3) A?, c = 20.997 (4) A?, β = 98.69 (2)°; Z = 4; 388 parameters were refined on 4901 reflections with I > 3σ(I) to yield R = 0.036 and Rw = 0.049.