212192-84-2

Upstream product

• 212192-83-1 ethyl 4,6-di-O-benzyl-2,3-di-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 212192-82-0 ethyl 2,3:4,6-di-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 151669-30-6 ethyl 2,3-di-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 7473-36-1 ethyl 1-thio-α-D-mannopyranoside 
• 870195-60-1 ethyl 6-O-acetyl-1-thio-α-D-mannopyranoside 
• 78-39-7 Triethyl orthoacetate 
• 187152-88-1 ethyl 4,6-di-O-benzyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 870195-62-3 ethyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 870195-61-2 ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl-(1->3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 212192-85-3 ethyl-2,3,4,6-tetra-O-benzyl-1-thio-α-D-galactopyranosyl-(1 - 3)-2-O-acetyl-4,6-di-O-benzyl-1-thio-α-D-mannopyranoside 

Relevant academic research and scientific papers

Synthesis of the tetrasaccharide α-D-Glcp-(1→3)-α-D-Manp- (1→2)-α-D-Manp-(1→2)-α-D-Manp recognized by Calreticulin/Calnexin

The title compound as its methyl glycoside was efficiently synthesized using a block synthesis approach. Halide-assisted glycosidations between 6-O-acetyl-2,3,4-tri-O-benzyl-α-d-glucopyranosyl iodide and ethyl 2-O-acetyl-4,6-di-O-benzyl-1-thio-α-d-mannopy

Synthesis of a di- and a trisaccharide related to the antigen from Klebsiella type 43

Starting from D-galactose, D-mannose and D-glucose methyl α-D- galactopyranosyl-(1→3)-α-D-mannopyranosyl-(1→2)-α-D-mannopyranoside and allyl β-D-mannopyranosyl-(1→4)-β-D-glucopyranosyl uronate were synthesised in a highly stereoselective manner.