2123-87-7Relevant academic research and scientific papers
REACTIVITY OF CARBOXYLIC ACID ANHYDRIDES IN THE ACYLATION OF TERT-BUTYL HYDROPEROXIDE IN BENZENE
Antonovskii, V. L.,Zhitina, L. V.,Emelin, Yu. D.,Komarova, V. I.
, p. 623 - 626 (2007/10/02)
The kinetics of the acylation of tert-butyl hydroperoxide with carboxylic acid anhydrides (RCO2)O (R = C5H11, CH3, C6H5, CH2Cl) in benzene were studied by GLC from the accumulation of tert-butylperoxy esters.Increase in the electron-withdrawing characteristics of the substituent R in the aliphatic series leads to an increase in the reactivity of the anhydride.The steric effect of the group R does not show up appreciably.The enthalpy and entropy of activation were determined.
