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Tert-butyl 2-bromobenzoperoxoate is a chemical compound with the molecular formula C10H11BrO3. It is a colorless to pale yellow crystalline solid, often used as a reagent in organic synthesis. tert-butyl 2-bromobenzoperoxoate is known for its ability to act as a selective brominating agent, particularly in the bromination of alkenes and alkynes. It is also used in the preparation of various organic compounds, such as pharmaceuticals and agrochemicals, due to its reactivity and stability. The compound is sensitive to heat and light, and should be handled with care, typically under an inert atmosphere to prevent decomposition. Its use in chemical reactions is governed by its ability to transfer bromine atoms, making it a valuable tool in synthetic chemistry.

2123-94-6

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2123-94-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2123-94-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,2 and 3 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 2123-94:
(6*2)+(5*1)+(4*2)+(3*3)+(2*9)+(1*4)=56
56 % 10 = 6
So 2123-94-6 is a valid CAS Registry Number.

2123-94-6Downstream Products

2123-94-6Relevant academic research and scientific papers

Bu4NI-catalyzed construction of tert-butyl peresters from alcohols

Zhang, Hui,Dong, Dao-Qing,Hao, Shuang-Hong,Wang, Zu-Li

, p. 8465 - 8468 (2016)

A new method for the synthesis of tert-butyl peresters directly from available alcohols catalyzed by Bu4NI at room temperature in an aqueous system was developed. Additionally, allylic esters could also be obtained by combing this method and Kharasch-Sosnovsky reaction via a two-step one-pot procedure.

Synthesis of tert-butyl peresters from aldehydes by Bu4NI- catalyzed metal-free oxidation and its combination with the Kharasch-Sosnovsky reaction

Wei, Wei,Zhang, Chao,Xu, Yuan,Wan, Xiaobing

supporting information; experimental part, p. 10827 - 10829 (2011/11/05)

A new tert-butyl peresters synthesis directly from aldehydes and TBHP was developed via Bu4NI-catalyzed aldehyde C-H oxidation. Mechanistic studies suggest that the protocol proceeds via a radical process. Combining the method with the Kharasch-Sosnovsky reaction offers a practical approach for the synthesis of allylic esters from simple aldehydes and alkenes via a two-step one-pot procedure.

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