21230-15-9Relevant academic research and scientific papers
Dithioacetal Exchange: A New Reversible Reaction for Dynamic Combinatorial Chemistry
Orrillo, A. Gastón,Escalante, Andrea M.,Furlan, Ricardo L. E.
, p. 6746 - 6749 (2016)
Reversibility of dithioacetal bond formation is reported under acidic mild conditions. Its utility for dynamic combinatorial chemistry was explored by combining it with orthogonal disulfide exchange. In such a setup, thiols are positioned at the intersection of both chemistries, constituting a connecting node between temporally separated networks. In reverse: Reversibility of dithioacetal bond formation is reported under acidic mild conditions (see figure). Its utility for dynamic combinatorial chemistry was explored by combining it with orthogonal disulfide exchange. In such a setup, thiols are positioned at the intersection of both chemistries, constituting a connecting node between temporally separated networks.
