Welcome to LookChem.com Sign In|Join Free

CAS

  • or

110-66-7

Post Buying Request

110-66-7 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

110-66-7 Usage

Chemical Properties

clear colorless liquid; meaty aroma. slightly soluble in water, easily soluble in alcohol and ether.

Uses

Different sources of media describe the Uses of 110-66-7 differently. You can refer to the following data:
1. 1-Pentanethiol is a raw material for organic synthesis. It is mainly used in the organic synthesis of sulfur compounds.
2. 1-Pentanethiol can be used as additives for hair coloring agents.

Preparation

1-Pentanethiol is synthesized from n-pentyl alcohol and hydrogen sulfide catalyzed by thorium dioxide.

Aroma threshold values

High strength odor; recommend smelling in a 0.10% solution or less.

General Description

1-Pentanethiol appears as a clear colorless to light-yellow liquid with an offensive odor. Flash point 65°F. Less dense than water and insoluble in water. Hence floats on water. Vapors are heavier than air. May be toxic by inhalation.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

1-Pentanethiol is incompatible with oxidizing agents, reducing agents, alkali metals, calcium hypochlorite, concentrated nitric acid .

Health Hazard

Inhalation may cause nausea because of offensive odor. Contact with eyes or skin causes slight irritation. Ingestion may cause vomiting.

Safety Profile

Moderately toxic by inhalation. A weak sensitizer and allergen. Local contact may cause contact dermatitis. A flammable liquid and dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidming materials. Hypergolic reaction with concentrated nitric acid. To fight fire, use foam, CO2, dry chemical. See also MERCAPTANS

Purification Methods

Dissolve the thiol in aqueous 20% NaOH, then extract with a small amount of diethyl ether. The aqueous solution is acidified slightly with 15% H2SO4, and the thiol is distilled out, dried with CaSO4 or CaCl2, and fractionally distilled under nitrogen. [Ellis & Reid J Am Chem Soc 54 1674 1932, Beilstein 1 IV 1453.]

Check Digit Verification of cas no

The CAS Registry Mumber 110-66-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 0 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 110-66:
(5*1)+(4*1)+(3*0)+(2*6)+(1*6)=27
27 % 10 = 7
So 110-66-7 is a valid CAS Registry Number.
InChI:InChI=1/C5H12S/c1-2-3-4-5-6/h6H,2-5H2,1H3

110-66-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (L04330)  1-Pentanethiol, 97%   

  • 110-66-7

  • 25g

  • 405.0CNY

  • Detail
  • Alfa Aesar

  • (L04330)  1-Pentanethiol, 97%   

  • 110-66-7

  • 100g

  • 1189.0CNY

  • Detail

110-66-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-Pentanethiol

1.2 Other means of identification

Product number -
Other names Amyl Mercaptan

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110-66-7 SDS

110-66-7Synthetic route

1-thiocyanatopentane
32446-40-5

1-thiocyanatopentane

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With tetraphosphorus decasulfide In toluene for 1.5h; Reflux;87%
hexanethioic acid S-pentyl ester

hexanethioic acid S-pentyl ester

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With titanium tetrachloride; zinc In dichloromethane at 25℃; for 0.166667h;85%
C8H16O2S

C8H16O2S

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol at 20℃; for 1h;70%
1-Chloropentane
543-59-9

1-Chloropentane

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With tetraethylammonium iodide; 1-(2-hydroxyethyl)-4,6-diphenylpyridin-2-thione In acetonitrile for 26h; Ambient temperature;61%
pentan-1-ol
71-41-0

pentan-1-ol

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With phosphorous (V) sulfide; benzene Erhitzen des Reaktionsprodukts auf 190grad;
1-Bromopentane
110-53-2

1-Bromopentane

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With sodium hydrogensulfide; ethanol
With ethanol; potassium hydrosulfide
With potassium hydrosulfide
1-Bromopentane
110-53-2

1-Bromopentane

thiourea
17356-08-0

thiourea

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With water Zersetzen des Thiuroniumsalzes mit starker KOH auf dem Wasserbad;
cyano-dithiocarbonimidic acid dipentyl ester
56342-26-8

cyano-dithiocarbonimidic acid dipentyl ester

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With hydrogenchloride
piperidine
110-89-4

piperidine

A

sulfure de pentamethylene
1613-51-0

sulfure de pentamethylene

B

2-methylthiolane
1795-09-1

2-methylthiolane

C

pyridine
110-86-1

pyridine

D

1-pentylpiperidine
10324-58-0

1-pentylpiperidine

E

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With hydrogen sulfide; hydrogen; sulfidized Ni-W at 300℃; under 105008 Torr; for 5h; Product distribution;A n/a
B n/a
C 0.59 % Chromat.
D 3.59 % Chromat.
E n/a
4-pentenyl-1-amine
22537-07-1

4-pentenyl-1-amine

A

sulfure de pentamethylene
1613-51-0

sulfure de pentamethylene

B

2-methylthiolane
1795-09-1

2-methylthiolane

C

diamyl sulfide
872-10-6

diamyl sulfide

D

n-pentanethiol
110-66-7

n-pentanethiol

E

pent-4-ene-1-thiol
17651-37-5

pent-4-ene-1-thiol

Conditions
ConditionsYield
With hydrogen sulfide; hydrogen; sulfidized Ni-W at 300℃; for 5h; Product distribution;
1-pentanesulfonic acid
35452-30-3

1-pentanesulfonic acid

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With diphosphorus pentasulfide; water 1.) sulfolane, 90 deg C for 24 h; Yield given. Multistep reaction;
1-pentyl tosylate
4450-76-4

1-pentyl tosylate

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With diphosphorus pentasulfide; lithium aluminium tetrahydride 1.) sulfolane, 90 deg C for 24 h 2.) ether, room temperature for 30 min; Yield given. Multistep reaction;
1-pentanamine
110-58-7

1-pentanamine

A

diamyl sulfide
872-10-6

diamyl sulfide

B

n-pentanethiol
110-66-7

n-pentanethiol

C

Di-n-amylamine
2050-92-2

Di-n-amylamine

D

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen sulfide; hydrogen; sulfidized Ni-W at 300℃; for 5h; Product distribution;A n/a
B n/a
C 2.3 % Chromat.
D 3.2 % Chromat.
diamyl disulfide
112-51-6

diamyl disulfide

sodium hydrosulfide

sodium hydrosulfide

n-pentanethiol
110-66-7

n-pentanethiol

hydrogenchloride
7647-01-0

hydrogenchloride

dithiooxalodiimidic acid dipentyl ester

dithiooxalodiimidic acid dipentyl ester

A

n-pentanethiol
110-66-7

n-pentanethiol

B

S,S-dipentyl 1,2-ethanebisthioate
855395-51-6

S,S-dipentyl 1,2-ethanebisthioate

C

1-thio-oxalamic acid S-pentyl ester

1-thio-oxalamic acid S-pentyl ester

D

oxalic acid
144-62-7

oxalic acid

4-pentenyl-1-amine
22537-07-1

4-pentenyl-1-amine

A

sulfure de pentamethylene
1613-51-0

sulfure de pentamethylene

B

2-methylthiolane
1795-09-1

2-methylthiolane

C

methylbutane
78-78-4

methylbutane

D

n-pentanethiol
110-66-7

n-pentanethiol

E

2-Methyl-1-butene
563-46-2

2-Methyl-1-butene

F

pentane
109-66-0

pentane

G

1-butyl-1-propyl sulphide, ethyl 1-pentyl sulphide,2,3-benzothiphene, C5H10S2, C8H16S, C9H14S, C9H18S

1-butyl-1-propyl sulphide, ethyl 1-pentyl sulphide,2,3-benzothiphene, C5H10S2, C8H16S, C9H14S, C9H18S

Conditions
ConditionsYield
With hydrogen sulfide; hydrogen Product distribution;
1-penten
109-67-1

1-penten

A

pentane-2-thiol
2084-19-7

pentane-2-thiol

B

pentane-3-thiol
616-31-9

pentane-3-thiol

C

n-pentanethiol
110-66-7

n-pentanethiol

Conditions
ConditionsYield
With hydrogen sulfide; TK-554 catalyst at 120 - 220℃; Product distribution / selectivity;
2-Methylthiophene
554-14-3

2-Methylthiophene

A

2-methylthiolane
1795-09-1

2-methylthiolane

B

n-pentanethiol
110-66-7

n-pentanethiol

C

1-penten
109-67-1

1-penten

Conditions
ConditionsYield
With nonane; hydrogen
2-Methylthiophene
554-14-3

2-Methylthiophene

A

2-methylthiolane
1795-09-1

2-methylthiolane

B

n-pentanethiol
110-66-7

n-pentanethiol

C

1-penten
109-67-1

1-penten

D

pentane
109-66-0

pentane

Conditions
ConditionsYield
With nonane; hydrogen at 224.84℃;
2-Methylthiophene
554-14-3

2-Methylthiophene

A

n-pentanethiol
110-66-7

n-pentanethiol

B

1-penten
109-67-1

1-penten

Conditions
ConditionsYield
With nonane; platinum on alumina; hydrogen at 224.84℃;
n-pentanethiol
110-66-7

n-pentanethiol

mercury(II) nitrate

mercury(II) nitrate

bis(1-pentanethiolato)mercury(II)
4080-30-2

bis(1-pentanethiolato)mercury(II)

Conditions
ConditionsYield
In ethanol; water the thiol was added to soln. of Hg(NO3)2 in EtOH/H2O in a Schlenk tube; soln. was stirred for 12 h in the dark; ppt. was filtered off, washed with cold EtOH and dried in vacuo;100%
n-pentanethiol
110-66-7

n-pentanethiol

benzenesufonyl hydrazide
80-17-1

benzenesufonyl hydrazide

benzenethiosulfonic acid S-pentyl ester

benzenethiosulfonic acid S-pentyl ester

Conditions
ConditionsYield
With tert.-butylhydroperoxide; sodium iodide In acetonitrile at 25℃;100%
With tert.-butylhydroperoxide; sodium iodide In acetonitrile at 20℃; for 12h;99%
With ammonium iodide In acetonitrile at 20℃; for 3h; Electrochemical reaction;78%
n-pentanethiol
110-66-7

n-pentanethiol

diamyl disulfide
112-51-6

diamyl disulfide

Conditions
ConditionsYield
With water; dihydrogen peroxide In various solvent(s) at 20℃; for 0.166667h; Oxidation; Dimerization;99%
With aluminum oxide In neat (no solvent) for 0.333333h; Milling; chemoselective reaction;98%
With oxygen; SiO2-Cl In dichloromethane at 0℃; for 0.166667h;97%
n-pentanethiol
110-66-7

n-pentanethiol

propargyl bromide
106-96-7

propargyl bromide

pentyl propargyl thioether
77202-44-9

pentyl propargyl thioether

Conditions
ConditionsYield
Stage #1: n-pentanethiol With sodium hydroxide In dichloromethane for 1h;
Stage #2: propargyl bromide In dichloromethane; toluene for 2h;
99%
With potassium hydroxide
n-pentanethiol
110-66-7

n-pentanethiol

N,N-Dimethyl-2,4-bis(trifluoroacetyl)-1-naphthylamine
115975-33-2

N,N-Dimethyl-2,4-bis(trifluoroacetyl)-1-naphthylamine

2,2,2-Trifluoro-1-[4-pentylsulfanyl-3-(2,2,2-trifluoro-acetyl)-naphthalen-1-yl]-ethanone
127053-12-7

2,2,2-Trifluoro-1-[4-pentylsulfanyl-3-(2,2,2-trifluoro-acetyl)-naphthalen-1-yl]-ethanone

Conditions
ConditionsYield
In acetonitrile for 41h; Heating;99%
5-Hexen-1-ol
821-41-0

5-Hexen-1-ol

n-pentanethiol
110-66-7

n-pentanethiol

6-(pentylsulfanyl)hexan-1-ol

6-(pentylsulfanyl)hexan-1-ol

Conditions
ConditionsYield
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 20℃; for 3h;99%
n-pentanethiol
110-66-7

n-pentanethiol

(4S)-N-tert-butoxycarbonyl-4-[[(4'-methylbenzenesulfonyl)oxy]methyl]-2,2-dimethyl-1,3-oxazolidine
140645-28-9

(4S)-N-tert-butoxycarbonyl-4-[[(4'-methylbenzenesulfonyl)oxy]methyl]-2,2-dimethyl-1,3-oxazolidine

4(S)-2,2-dimethyl-4-(pentylthiomethyl)oxazolidine-3-carboxylic acid tert-butyl ester
935547-63-0

4(S)-2,2-dimethyl-4-(pentylthiomethyl)oxazolidine-3-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: n-pentanethiol With sodium hydride In N,N-dimethyl-formamide at 20℃;
Stage #2: (4S)-N-tert-butoxycarbonyl-4-[[(4'-methylbenzenesulfonyl)oxy]methyl]-2,2-dimethyl-1,3-oxazolidine In N,N-dimethyl-formamide at 40℃; for 1h;
99%
With sodium hydride In N,N-dimethyl-formamide at 60 - 80℃;
n-pentanethiol
110-66-7

n-pentanethiol

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

methyl (2R)-2-methyl-3-(pentylsulfanyl)propanoate

methyl (2R)-2-methyl-3-(pentylsulfanyl)propanoate

Conditions
ConditionsYield
With C47H57N4O4PS In diethyl ether at 20℃; for 24h; Michael Addition; enantioselective reaction;99%
n-pentanethiol
110-66-7

n-pentanethiol

tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

tert-butyl 3-(pentylthio)propanoate

tert-butyl 3-(pentylthio)propanoate

Conditions
ConditionsYield
Stage #1: n-pentanethiol In acetonitrile at 20℃; for 0.0833333h;
Stage #2: tert-Butyl acrylate In acetonitrile at 50 - 60℃; for 0.25h;
99%
With potassium carbonate In dichloromethane at 20℃; for 20h; Michael Addition; Inert atmosphere;
tert-butyl diphenylmethylsilylglyoxylate

tert-butyl diphenylmethylsilylglyoxylate

n-pentanethiol
110-66-7

n-pentanethiol

C24H34O3SSi

C24H34O3SSi

Conditions
ConditionsYield
With C39H60N4O4; yttrium(III) trifluoromethanesulfonate In dichloromethane at -60℃; for 4h; enantioselective reaction;99%
n-pentanethiol
110-66-7

n-pentanethiol

2-(4-allyl-1-piperazinyl)-4-chloroquinazoline
122009-56-7

2-(4-allyl-1-piperazinyl)-4-chloroquinazoline

2-(4-Allyl-piperazin-1-yl)-4-pentylsulfanyl-quinazoline
134249-89-1

2-(4-Allyl-piperazin-1-yl)-4-pentylsulfanyl-quinazoline

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 0℃;98%
n-pentanethiol
110-66-7

n-pentanethiol

12-Chloro-8,9,10,11-tetrahydro-7H-benzo[4,5]imidazo[1,2-a]cyclohepta[d]pyridine-6-carbonitrile
163080-54-4

12-Chloro-8,9,10,11-tetrahydro-7H-benzo[4,5]imidazo[1,2-a]cyclohepta[d]pyridine-6-carbonitrile

12-Pentylsulfanyl-8,9,10,11-tetrahydro-7H-benzo[4,5]imidazo[1,2-a]cyclohepta[d]pyridine-6-carbonitrile

12-Pentylsulfanyl-8,9,10,11-tetrahydro-7H-benzo[4,5]imidazo[1,2-a]cyclohepta[d]pyridine-6-carbonitrile

Conditions
ConditionsYield
With 5-bromo-2'-deoxyuridine In benzene for 4h; Ambient temperature;98%
n-pentanethiol
110-66-7

n-pentanethiol

prop-2-en-1-yl 2,3,4-tri-O-acetyl-α-L-fucopyranoside
191540-37-1

prop-2-en-1-yl 2,3,4-tri-O-acetyl-α-L-fucopyranoside

Acetic acid (2S,3R,4R,5S,6R)-3,5-diacetoxy-2-methyl-6-(3-pentylsulfanyl-propoxy)-tetrahydro-pyran-4-yl ester

Acetic acid (2S,3R,4R,5S,6R)-3,5-diacetoxy-2-methyl-6-(3-pentylsulfanyl-propoxy)-tetrahydro-pyran-4-yl ester

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In 1,4-dioxane at 75℃;98%
n-pentanethiol
110-66-7

n-pentanethiol

bis-(dimethylamino)methane
51-80-9

bis-(dimethylamino)methane

N,N-dimethyl-1-(pentylsulfanyl)methaneamine
1369272-96-7

N,N-dimethyl-1-(pentylsulfanyl)methaneamine

Conditions
ConditionsYield
With samarium(III) chloride hexahydrate at 60℃; for 1.5h; Inert atmosphere; chemoselective reaction;98%
4-(morpholinomethyl)morpholine
5625-90-1

4-(morpholinomethyl)morpholine

n-pentanethiol
110-66-7

n-pentanethiol

N-(pentylsulfanylmethyl)morpholine
1394913-18-8

N-(pentylsulfanylmethyl)morpholine

Conditions
ConditionsYield
With zinc(II) chloride dihydrate at 60℃; for 6h; Temperature; Reagent/catalyst; Time;98%
n-pentanethiol
110-66-7

n-pentanethiol

4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

S-pentyl 4-methylbenzothioate
1034012-61-7

S-pentyl 4-methylbenzothioate

Conditions
ConditionsYield
With Phenazin; 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 90℃; for 12h; Temperature; Schlenk technique;98%
n-pentanethiol
110-66-7

n-pentanethiol

tert-butyl (E)-crotonate
79218-15-8

tert-butyl (E)-crotonate

C13H26O2S

C13H26O2S

Conditions
ConditionsYield
With C49H53N4O4PS In diethyl ether at 0℃; enantioselective reaction;98%
n-pentanethiol
110-66-7

n-pentanethiol

C19H21NO5

C19H21NO5

C24H33NO5S

C24H33NO5S

Conditions
ConditionsYield
Stage #1: n-pentanethiol; C19H21NO5 In dichloromethane for 0.5h;
Stage #2: With Dimethyl(phenyl)phosphine In dichloromethane at 20℃; for 3h;
98%
thiophene
110-01-0

thiophene

n-pentanethiol
110-66-7

n-pentanethiol

dimethyl amine
124-40-3

dimethyl amine

Thiram
137-26-8

Thiram

Conditions
ConditionsYield
Stage #1: thiophene; n-pentanethiol; dimethyl amine With sodium nitrate at 24℃; for 2.83333h;
Stage #2: With lead(IV) tetraacetate; nickel dibromide at 18℃; for 4h; Temperature;
97.8%
furfural
98-01-1

furfural

n-pentanethiol
110-66-7

n-pentanethiol

2-(bis(pentylthio)methyl)furan

2-(bis(pentylthio)methyl)furan

Conditions
ConditionsYield
With H-beta(19) zeolite In neat (no solvent) at 23℃; for 6h;97%
With graphene oxide In neat (no solvent) at 20℃; for 3h; Green chemistry; chemoselective reaction;92%
triethylsilane
617-86-7

triethylsilane

n-pentanethiol
110-66-7

n-pentanethiol

triethyl(pentylthio)silane
33577-01-4

triethyl(pentylthio)silane

Conditions
ConditionsYield
With [RuCl(η5-(3-phenyl)indenyl)(PPh3)2] In toluene at 80℃; for 16h; Glovebox;96%
(i) NiCl2, (ii) /BRN= 1730979/; Multistep reaction;
n-pentanethiol
110-66-7

n-pentanethiol

4-Chloro-2-(4-methyl-1-piperazinyl)quinazoline
39213-06-4

4-Chloro-2-(4-methyl-1-piperazinyl)quinazoline

2-(4-Methyl-piperazin-1-yl)-4-pentylsulfanyl-quinazoline
129663-85-0

2-(4-Methyl-piperazin-1-yl)-4-pentylsulfanyl-quinazoline

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide96%
n-pentanethiol
110-66-7

n-pentanethiol

1-pentanesulfinic acid
76008-87-2

1-pentanesulfinic acid

Conditions
ConditionsYield
With 3,3-dimethyldioxirane In dichloromethane at -40℃;96%
n-pentanethiol
110-66-7

n-pentanethiol

allyl methyl carbonate
35466-83-2

allyl methyl carbonate

allyl pentyl sulfide
3393-13-3

allyl pentyl sulfide

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)(pentamethylcyclopentadiene)ruthenium(II) In acetonitrile at 20℃; for 1h; Alkylation;96%
n-pentanethiol
110-66-7

n-pentanethiol

1,2,4,5-tetrabromomethylbenzene
15442-91-8

1,2,4,5-tetrabromomethylbenzene

1,2,4,5-tetrakis(pentylsulfanylmethyl)benzene
261912-38-3

1,2,4,5-tetrakis(pentylsulfanylmethyl)benzene

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 25℃; for 12h; Substitution;96%
1-benzhydryl-3-azetidinyl methanesulfonate
33301-41-6

1-benzhydryl-3-azetidinyl methanesulfonate

n-pentanethiol
110-66-7

n-pentanethiol

1-(diphenylmethyl)-3-(pentylthio)azetidine
1309207-50-8

1-(diphenylmethyl)-3-(pentylthio)azetidine

Conditions
ConditionsYield
Stage #1: n-pentanethiol With sodium hydride In dimethyl sulfoxide at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 1-benzhydryl-3-azetidinyl methanesulfonate In dimethyl sulfoxide at 0 - 20℃;
96%
n-pentanethiol
110-66-7

n-pentanethiol

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

C10H20OS

C10H20OS

Conditions
ConditionsYield
With (N,N′-bis(2,4,6-trimethylphenyl)imidazole-2-ylidene)Pd(acac)Cl; 3-isopropyl-6-methylcyclohexa-1,4-diene; triethylamine In neat (no solvent) at 100℃; for 8h; Green chemistry; regioselective reaction;96%
n-pentanethiol
110-66-7

n-pentanethiol

5-hexynonitrile
14918-21-9

5-hexynonitrile

C11H19NS

C11H19NS

Conditions
ConditionsYield
With (N,N′-bis(2,4,6-trimethylphenyl)imidazole-2-ylidene)Pd(acac)Cl; 3-isopropyl-6-methylcyclohexa-1,4-diene; triethylamine In neat (no solvent) at 100℃; for 8h; Green chemistry; regioselective reaction;96%
n-pentanethiol
110-66-7

n-pentanethiol

epichlorohydrin
106-89-8

epichlorohydrin

3-chloro-1-pentylsulfanyl-propan-2-ol
26404-98-8

3-chloro-1-pentylsulfanyl-propan-2-ol

Conditions
ConditionsYield
With dimethylbromosulphonium bromide at 20℃; for 0.0666667h; regioselective reaction;95%
With zinc(II) chloride
n-pentanethiol
110-66-7

n-pentanethiol

methyl (3-phenylprop-2-yn-1-yl) carbonate
420121-38-6

methyl (3-phenylprop-2-yn-1-yl) carbonate

pentyl 3-phenylprop-2-ynyl sulfide

pentyl 3-phenylprop-2-ynyl sulfide

Conditions
ConditionsYield
With N-methylcyclohexylamine; chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) at 100℃; for 8h;95%

110-66-7Related news

Experimental investigation on thermochemical sulfate reduction in the presence of 1-Pentanethiol (cas 110-66-7) at 200 and 250 °C: Implications for in situ TSR processes occurring in some MVT deposits08/20/2019

Organic sulfur compounds are ubiquitous in natural oil and gas fields and moderate-low temperature sulfide ore deposits. Previous studies have shown that organic sulfur compounds are important in enhancing the rates of thermochemical sulfate reduction (TSR) reactions, but the details of these re...detailed

110-66-7Relevant articles and documents

Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols

Maurya, Chandra Kant,Mazumder, Avik,Gupta, Pradeep Kumar

supporting information, p. 1184 - 1188 (2017/07/03)

In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P2S5) in refluxing toluene. The method avoids the use of expensive and hazardous transition metals and harsh reducing agents, as required by reported methods, and provides an attractive alternative to the existing methods for the conversion of organic thiocyanates to thiols.

Reductive removal of methoxyacetyl protective group using sodium borohydride

Gadekar, Pradip K.,Hoermann, Maryann,Corbo, Faith,Sharma, Rajiv,Sarveswari,Roychowdhury, Abhijit

, p. 503 - 506 (2014/01/06)

Herein, we have developed a mild and selective reductive deprotection method for the MAc protected alcohols using sodium borohydride. The new deprotection conditions provide a complete orthogonality between O-MAc and other protecting groups such as tert-butyl ester, N-Boc, Fmoc, Cbz, O-TBDMS, N-benzyl, O-benzyl, O-acetyl, N-acetyl, N-MAc, etc. In addition to O-MAc deprotection, this method is also applicable for S-MAc deprotection.

Method of making 2-thiols

-

Page/Page column 5, (2008/06/13)

A process for selectively making 2-thiols from alpha olefins is described. The process includes contacting a linear or branched alpha olefin having with H2S in the presence of a catalyst and recovering the 2-thiol from a product mixture. The catalyst includes a support and at least one metal selected from Group IIIA-VIIIA and the branched olefin is branched at the 3-position or higher with respect to the olefin double bond. Compositions wherein the 2-thiols are substantially free of 1 -thiol and 3-thiol isomers are also described.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 110-66-7