212370-47-3Relevant academic research and scientific papers
First total synthesis and absolute configuration of the styryl lactone gonioheptolide A
Gupta, Shuchi,Rajagopalan, Murali,Alhamadsheh, Mamoun M.,Tillekeratne, L. M. Viranga,Hudson, Richard A.
, p. 3512 - 3518 (2008/09/20)
Efficient asymmetric syntheses of both naturally occurring and non-naturally occurring enantiomers of gonioheptolide A are reported. The absolute configuration of (+)-gonioheptolide A was established by NOESY, Mosher ester analysis, and comparison with the specific rotation of the isolated (+)-gonioheptolide A. Georg Thieme Verlag Stuttgart.
Polymer-bound palladium-catalyzed coupling of allylic alcohols with hypervalent iodonium salts
Jang, Su-Bum
, p. 4421 - 4424 (2007/10/03)
The polymer-bound palladium catalyzed cross-coupling reaction of allylic alcohols with hypervalent iodonium sails to form carbon-carbon bonds was achieved at room temperature under extremely mild and aqueous conditions even in the absence of base with very high activity in the Stille coupling reaction. The polymeric catalyst can be easily separated from a reaction mixture and reused more than 10 times with no decrease in activity.
