367520-83-0

Upstream product

• 143878-62-0 (4S,5S)-4-[(benzyloxy)methyl]-2,2-dimethyl-5-vinyl-1,3-dioxolane 
• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 
• 1449-46-3 benzyltriphenylphosphonium bromide 

Downstream Products

• 212370-47-3 (E,2S,3S)-1-(benzyloxy)-5-phenylpent-4-ene-2,3-diol 

Relevant academic research and scientific papers

First total synthesis and absolute configuration of the styryl lactone gonioheptolide A

Efficient asymmetric syntheses of both naturally occurring and non-naturally occurring enantiomers of gonioheptolide A are reported. The absolute configuration of (+)-gonioheptolide A was established by NOESY, Mosher ester analysis, and comparison with the specific rotation of the isolated (+)-gonioheptolide A. Georg Thieme Verlag Stuttgart.

Palladium-catalyzed coupling reaction of vinyl epoxides, diol acetonides, and diol carbonates with organobismuth compounds

The palladium-catalyzed arylation reaction of vinyl epoxides with organobismuth compounds afforded the aryl-substituted (E)-allylic alcohols via ring opening of epoxides. Alternatively, the palladium-catalyzed reaction of diol acetonides and carbonates wi