212498-15-2

Upstream product

• 83095-83-4 [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 
• 68558-86-1 thallium(I) pentafluorobenzoate 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 894105-17-0 [Pt(2,6-dimethylphenyl isocyanide)(C₆F₅)(1,2-bis(diphenylphosphino)ethane)]O₃SCF₃ 
• 894105-01-2 [Pt(H₂O)(C₆F₅)(1,2-bis(diphenylphosphino)ethane)]O₃SCF₃ 

Relevant academic research and scientific papers

Second-generation electron-poor platinum(II) complexes as efficient epoxidation catalysts for terminal alkenes with hydrogen peroxide

The preparation and characterization of second-generation electron-poor Pt(II) complexes of general formula [(P-P)Pt(C6F5)(H 2O)][X], 1a-h (P-P = diphosphine, X = BF4, OTf), bearing a pentafluorophenyl ligand is

The synthesis by decarboxylation reactions and crystal structures of 1,n-bis(diphenylphosphino)alkane(pentafluorophenyl)-platinum(II) complexes

Decarboxylation reactions between the complexes cis-[PtCl2L] (L = 1,n-bis(diphenylphosphino)-ethane (n = 2, dppe), -propane (n = 3, dppp) or -butane (n = 4, dppb)) and thallium(I) pentafluorobenzoate in pyridine give cis-[PtCl(C6F5)L] and cis-[Pt(C6F 5)2L] complexes in high yields with short reaction times. X-ray crystal structures of cis-[PtCl(C6F5)(dppe)] ·0.5 C5H5N, cis-[PtCl(C6F 5)(dppp)], cis-[PtCl(C6F5)(dppb)]·C 3H6O. cis-[Pt(C6F5)2L] (L = dppe, dppp and dppb) and the reactants cis-[PtCl2(dppp)] (as a CH2Cl2 solvate) and cis-[PtCl2(dppb)] show monomeric structures with chelating diphosphine ligands in all cases rather than dimers with bridging diphosphines. 31P NMR data are consistent with these structures in solution.