21250-19-1

Upstream product

• 554-00-7 2,4-Dichloroaniline 

Downstream Products

• 51658-65-2 1-(2,4-dichloro-phenylimino)-7-nitro-5-trifluoromethyl-1H-1λ⁴-benzothiazole-2-carboxylic acid ethyl ester 
• 51658-67-4 1-(2,4-dichloro-phenylimino)-5,7-dinitro-1H-1λ⁴-benzothiazole-2-carboxylic acid ethyl ester 
• 100153-91-1 2-(2,4-dichloro-phenyl)-1-oxo-4,4-diphenyl-1λ⁴-[1,2]thiazetidin-3-one 
• 100410-13-7 2'-(2,4-dichloro-phenyl)-1'-oxo-1'λ⁴-spiro[fluorene-9,4'-[1,2]thiazetidin]-3'-one 

Relevant academic research and scientific papers

Reaction of electron-deficient N-sulfinylanilines with chiral α-hydroxy acids: A new process for the synthesis of enantiomerically pure α-hydroxy amides

A practical procedure to prepare enantiomerically pure α-hydroxy amides from chiral α-hydroxy acids and electron-deficient anilines via N-sulfinylaniline derivatives has been developed. (C) 2000 Elsevier Science Ltd.

Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]

Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.