21250-85-1

Basic information

• Product Name: N-Methoxyethanimidic acid ethyl ester
• Synonyms: N-Methoxyethanimidic acid ethyl ester
• CAS NO: 21250-85-1
• Molecular Formula: C₅H₁₁NO₂
• Molecular Weight: 117.1463
• Mol File: 21250-85-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 107°Cat760mmHg
• Flash Point: 20.8°C
• Appearance: /
• Density: 0.91g/cm³
• Vapor Pressure: 32.3mmHg at 25°C
• Refractive Index: 1.398
• CAS DataBase Reference: N-Methoxyethanimidic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-Methoxyethanimidic acid ethyl ester(21250-85-1)
• EPA Substance Registry System: N-Methoxyethanimidic acid ethyl ester(21250-85-1)

Safety Data

• Hazardous Substances Data: 21250-85-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C5H11NO2/c1-4-8-5(2)6-7-3/h4H2,1-3H3

Upstream product

• 10576-12-2 ethyl acetohydroximate 
• 74-88-4 methyl iodide 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 95614-77-0 (2S,3S)-3-Hydroxy-N-methoxy-3-phenyl-2-((R)-toluene-4-sulfinyl)-propionimidic acid ethyl ester 
• 95614-77-0 (2S,3R)-3-Hydroxy-N-methoxy-3-phenyl-2-((R)-toluene-4-sulfinyl)-propionimidic acid ethyl ester 
• 95614-78-1 (2S,3S)-3-Hydroxy-N-methoxy-4-methyl-2-((R)-toluene-4-sulfinyl)-pentanimidic acid ethyl ester 
• 95614-78-1 (2S,3R)-3-Hydroxy-N-methoxy-4-methyl-2-((R)-toluene-4-sulfinyl)-pentanimidic acid ethyl ester 
• 95614-81-6 (S)-3-Hydroxy-N-methoxy-3-phenyl-propionimidic acid ethyl ester 
• 95614-81-6 (R)-3-Hydroxy-N-methoxy-3-phenyl-propionimidic acid ethyl ester 

Relevant articles and documents

ETHYL-(R)-(4-METHYLPHENYLSULFINYL)-N-METHOXY ACETIMIDATE, A USEFUL CHIRAL ACETATE EQUIVALENT IN ALDOL TYPE CONDENSATIONS.

Ethyl N-methoxyacetimidate was metallated by lithium amides and reacted with (-)-(S)-menthyl p-toluenesulfinate to afford, in excellent yield, (R)-(4-methylphenylsulfinyl)-ethyl-N-methoxy acetimidate (2).Compound (2) was tested in aldol-type condensations