212554-36-4Relevant academic research and scientific papers
A practical preparation of 2-hydroxymethyl-2-cyclopenten-1-one by Morita-Baylis-Hillman reaction
Ito, Hisanaka,Takenaka, Yosuke,Fukunishi, Shouhei,Iguchi, Kazuo
, p. 3035 - 3038 (2005)
Tributylphosphine or dimethylphenylphosphine (1-5 mol%) catalyzed the Morita-Baylis-Hillman reaction of 2-cyclo-penten-1-one (1) with 1.2 equivalents of formalin proceeded nicely to give 2-hydroxymethyl-2-cyclopenten-1-one (2) within a short period and in
DMAP-catalyzed hydroxymethylation of 2-cyclohexenones in aqueous medium through baylis-hillman reaction
Rezgui, Farhat,El Gaied, Mohamed Moncef
, p. 5965 - 5966 (2007/10/03)
Reaction of 2-cyclohexenones 1a-d with aqueous formaldehyde, catalyzed by DMAP in THF, affords the corresponding 2-(hydroxymethyl)-2-cyclohexenones 2a-d in good yields.
