212890-84-1

Basic information

• Product Name: (S)-2-[(Diphenylphosphanyl)-methyl]-4,4-dimethyl-pyrrolidine
• Synonyms: (S)-2-[(Diphenylphosphanyl)-methyl]-4,4-dimethyl-pyrrolidine
• CAS NO: 212890-84-1
• Molecular Weight: 297.38
• Mol File: 212890-84-1.mol

Chemical Properties

• CAS DataBase Reference: (S)-2-[(Diphenylphosphanyl)-methyl]-4,4-dimethyl-pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-[(Diphenylphosphanyl)-methyl]-4,4-dimethyl-pyrrolidine(212890-84-1)
• EPA Substance Registry System: (S)-2-[(Diphenylphosphanyl)-methyl]-4,4-dimethyl-pyrrolidine(212890-84-1)

Safety Data

• Hazardous Substances Data: 212890-84-1(Hazardous Substances Data)

Upstream product

• 184699-47-6 (S)-(-)-tert-butyl 4,4-dimethyl-2-[((4-methylphenyl)sulfonyloxy)methyl]pyrrolidinecarboxylate 
• 212890-86-3 (S)-(-)-tert-butyl 2-(hydroxymethyl)-4,4-dimethylpyrrolidinecarboxylate 
• 212890-85-2 (S)-(+)-(4,4-dimethylpyrrolidin-2-yl)methan-1-ol 
• 156088-46-9 (5S)-3,3-dimethyl-5-hydroxymethylpyrrolidin-2-one 
• 212890-87-4 (S)-(-)-tert-butyl 2-[(diphenylphosphino)methyl]-4,4-dimethylpyrrolidinecarboxylate 

Relevant articles and documents

Structural requirements of an external, chiral amidophosphine ligand for asymmetric reaction of an organocopper reagent

Three types of an external, chiral amide ligand, 2-6, were prepared and examination of their behavior in an asymmetric conjugate addition reaction of lithium dimethylcuprate with chalcone revealed to possibility for steric tuning to realize high selectivity.