213331-27-2Relevant academic research and scientific papers
Ruthenium Catalyzed Rearrangement of Ene-cyclopropenes. Divergent Reaction Pathways
López-Rodríguez, Alberto,Domínguez, Gema,Pérez-Castells, Javier
, p. 924 - 933 (2019)
The reaction of ene-cyclopropenes with Cp?RuCl(cod) leads to alkenyl bicyclo[3.1.0]hexanes, bicyclo[4.1.0]heptanes, and bicyclo[5.1.0]octanes. This reaction involves a reverse regioselectivity in the cyclopropene opening than with gold chlorides. With gem
Enamide-Olefin Ring-Closing Metathesis
Kinderman, Sape S.,Van Maarseveen, Jan H.,Schoemaker, Hans E.,Hiemstra, Henk,Rutjes, Floris P. J. T.
, p. 2045 - 2047 (2007/10/03)
(matrix presented) The first examples of ring-closing metathesis reactions of olefin-containing enamides using ruthenium-based catalysts have been demonstrated. A preliminary investigation into the scope and limitations, leading to protected five- and six-membered cyclic enamides, will be presented.
