213460-12-9Relevant academic research and scientific papers
[3+2] Cycloaddition reactions of the phospha-alkyne, ButCP, with a transition metal trisulphide containing terminal thio ligands: Syntheses, crystal and molecular structures of [W(η5-(C5Me5)(S)(S2PCtBu)]2 and [W(η5-(C5Me5)(S)(S2C2 Ph2)]2
D'Arbeloff, Sarah E.,Hitchcock, Peter B.,Nixon, John F.,Nagasawa, Takayuki,Kawaguchi, Hiroyuki,Tatsumi, Kazuyuki
, p. 189 - 191 (1998)
The trisulphido complex [PPh4][W(η5-(C5Me5)(S)3], reacts with the phospha-alkyne ButCP and O2 to afford the dimeric complex [W(η5-(C5Me5)(S)(S2PCtBu)]2. Analogous reactions occur with the alkyne Ph2C2 to give [W(η5-(C5Me5)(S)(S2C2 Ph2)]2. The molecular structures of both complexes are presented and discussed.
