213919-41-6Relevant academic research and scientific papers
Reversible and irreversible conformational changes in poly(isocyanide)s: A remote stereoelectronic effect
Amabilino, David B.,Serrano, Jose-Luis,Veciana, Jaume
, p. 322 - 324 (2007/10/03)
Poly(isocyanide)s prepared by diastereoselective polymerisation of two chiral monomers, which differ only in the presence of a nitro-group adjacent to the stereogenic group, exhibit long range chiral induction, but a surprising influence of a remote subst
Long-range chiral induction in chemical systems with helical organization. Promesogenic monomers in the formation of poly(isocyanide)s and in the organization of liquid crystals
Amabilino, David B.,Ramos, Elena,Serrano, José-Luis,Sierra, Teresa,Veciana, Jaume
, p. 9126 - 9134 (2007/10/03)
The preparation of optically active poly(isocyanide)s derived from chiral promesogenic monomers is reported. Remarkably, the stereogenic carbon atom in the monomer is able to pass its chiral 'information' to the growing polymer backbone which is at least
