213991-96-9

Basic information

• Product Name: methyl 1-[2-(2-methoxycarbonylphenyl)-1-ethynyl]-2-naphthoate
• Synonyms: methyl 1-[2-(2-methoxycarbonylphenyl)-1-ethynyl]-2-naphthoate
• CAS NO: 213991-96-9
• Molecular Weight: 344.367
• Mol File: 213991-96-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 1-[2-(2-methoxycarbonylphenyl)-1-ethynyl]-2-naphthoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-[2-(2-methoxycarbonylphenyl)-1-ethynyl]-2-naphthoate(213991-96-9)
• EPA Substance Registry System: methyl 1-[2-(2-methoxycarbonylphenyl)-1-ethynyl]-2-naphthoate(213991-96-9)

Safety Data

• Hazardous Substances Data: 213991-96-9(Hazardous Substances Data)

Upstream product

• 33577-99-0 2-ethynyl-benzoic acid methyl ester 
• 89555-39-5 methyl 1-bromo-2-naphthalenecarboxylate 
• 107793-07-7 methyl 2-(2-trimethylsilyl-1-ethynyl)benzoate 
• 610-97-9 o-iodo-methyl-benzoic acid 

Downstream Products

• 223596-87-0 2-[4-(Triisopropylsilyl)but-2-yn-1-yl]-1-(2-{2-[4-(triisopropyl)but-3-yn-1-yl]phenyl}ethyn-1-yl)naphthalene 
• 223596-88-1 2-(But-2-yn-1-yl)-1-{2-[2-(but-3-yn-1-yl)phenyl]ethyn-1-yl}naphthalene 
• 223596-86-9 2-(Bromomethyl)-1-{2-[2-(bromomethyl)phenyl]ethyn-1-yl}naphthalene 
• 207673-34-5 4-Methyl-N-(prop-2-en-1-yl)-N-({1-[2-(2-{[N-(prop-2-yn-1-yl)-N-tosylamino]methyl}phenyl)ethyn-1-yl]-2-naphthyl}methyl)benzenesulfonamide 
• 207673-33-4 2-[(But-2-yn-1-yloxy)methyl]-1-(2-{2-[(but-2-yn-1-yloxy)methyl]phenyl}ethyn-1-yl)naphthalene 
• 223596-85-8 (1-{2-[2-(Hydroxymethyl)phenyl]ethyn-1-yl}-2-naphthyl)methanol 

Relevant articles and documents

Coupling reactions of ortho-substituted aryl halides with alkynes. The synthesis of functionalized 1-naphthyl-, 1-(1-naphthyl)-2-phenyl-, and 1,2- bis(1-naphthyl)acetylenes

Coupling of 2-functionalized 1-naphthyl halides with gaseous acetylene, (trialkylsilyl)acetylenes, and aryl acetylenes under Pd(PPh3)4 or Pd(PPh3)4/CuI catalysis has been investigated to prepare 1-naphthyl-, 1-