214077-90-4Relevant academic research and scientific papers
Hexahelicenophanes
Meier, Herbert,Schwertel, Manfred,Kolshorn, Heinz
, p. 2009 - 2019 (2013)
A reaction sequence was studied for the preparation of cyclophanes 12, which contain 2,7-bis(2-phenylethenyl)naphthalene chromophores and polymethylenedioxy chains of different length. The irradiation of 12 in the presence of I2 led then, by ox
Regioselective C-H arylation of imidazoles employing macrocyclic palladium(II) complex of organoselenium ligand
Gadwal, Jitendra,Joshi, Hemant,Kumar, Sunil,Makar, Parvesh,Singh, Sohan
, (2021/06/12)
In this report we have presented synthesis of a new air stable bidentate selenium ligand (L1) by the reaction of 1,8-bis(2-(chloromethyl)phenoxy)octane with sodium salt of diphenyl diselenide. The reaction of bidentate selenium ligand (L1) with Pd(CH
Ring-closing metathesis reaction-based synthesis of new classes of polyether macrocyclic systems
Naveen,Babu, Srinivasarao Arulananda
supporting information, p. 7758 - 7781 (2015/09/08)
Ring closing metathesis (RCM) reactions of suitable substrates having terminal olefins, which are assembled from various linkers and hydroxy benzaldehydes and syntheses of a wide range of 16-30 membered, new crown ether-type polyether, aza-polyether, bis aza-polyether macrocycles and dilactone moiety embedded polyether macrocycles (macrolides) are reported. After the ring-closure reaction, installation of different functional groups and functional group modification on the periphery of the synthesized polyether/crown ether macrocycles obtained in the RCM reactions are accomplished using the epoxidation, oxidation and catalytic hydrogenation-based synthetic transformations. Along this line, the syntheses of a variety of polyether macrocycles possessing epoxide or α-hydroxy ketone or 1,2-diol functionalities at the periphery have been shown. Furthermore, the synthesized α-hydroxy ketone functionality installed polyether macrocycles were subjected to the allylation and Reformatsky type reactions to obtain homoallyl alcohol moiety-based and lactone ring-appended polyether macrocycles.
