36247-32-2Relevant academic research and scientific papers
Oligo(ethylene glycol)-incorporated hybrid linear alkyl side chains for n-channel polymer semiconductors and their effect on the thin-film crystalline structure
Kim, Ran,Kang, Boseok,Sin, Dong Hun,Choi, Hyun Ho,Kwon, Soon-Ki,Kim, Yun-Hi,Cho, Kilwon
, p. 1524 - 1527 (2015)
Oligo(ethylene glycol)-incorporated hybrid linear alkyl side chains, serving as solubilizing groups, are designed and introduced into naphthalene-diimide-based n-channel copolymers. The synthesized polymers exhibit unipolar n-type operation with an electron mobility of up to 1.64 cm2 V-1 s-1, which demonstrates the usefulness of the hybrid side chains in polymer electronics applications.
Isotopically Sensitive Branching and Its Effect on the Observed Intramolecular Isotope Effects in Cytochrome P-450 Catalyzed Reactions:A New Method for the Estimation of Intrinsic Isotope Effects
Jones, Jeffrey P.,Korzekwa, Kenneth R.,Rettie, Allan E.,Trager, William F.
, p. 7074 - 7078 (1986)
Two selectively deuterated n-octanes (octane-1-2H3 and octane-1,2,3-2H7)were synthesized and subjected to hydroxylation by phenobarbital-induced rat liver microsomes and purified cytochrome P-450b.The results of these experiments provide evidence which cl
Light-driven rotary molecular motors on gold nanoparticles
Pollard, Michael M.,Ter Wiel, Matthijs K. J.,Van Delden, Richard A.,Vicario, Javier,Koumura, Nagatoshi,Van Den Brom, Coenraad R.,Meetsma, Auke,Feringa, Ben L.
supporting information; experimental part, p. 11610 - 11622 (2009/12/09)
We report the synthesis of unidirectional light-driven rotary molecular motors based on chiral overcrowded alkenes and their immobilisation on the surface of gold nanoparticles through two anchors. Using a combination of 1H and 13C N
Tethered PProDOTs: Conformationally restricted 3,4-propylenedioxythiophene based electroactive polymers
Walczak, Ryan M.,Cowart Jr., John S.,Reynolds, John R.
, p. 254 - 260 (2008/02/01)
Herein we report a complete family of conformationally restricted PProDOT derivatives with varying alkylene tether lengths. It was found that variation of the tether length and structure of the electropolymerizable monomer was successful in the fine-tuning of the electrochemical and optical properties of the subsequent material. It was found that the band gap of the materials could be varied between 1.94 and 2.26 eV, with the "sweet spot" for obtaining the maximum electronic band gap existing at the n = 6 tether length, while maintaining low redox potentials. It was also found that these polymers exhibited stable electrochromic behavior with colors varying from blue-purple to orange in their neutral states and transmissive in their doped states. The Royal Society of Chemistry 2007.
Synthesis of model long-chain ω-alkenyltrichlorosilanes and triethoxysilanes for the formation of self-assembled monolayers
Nguyen, Thanh Binh,Castanet, Anne-Sophie,Nguyen, Thi-Huu,Nguyen, Kim Phi Phung,Bardeau, Jean-Fran?ois,Gibaud, Alain,Mortier, Jacques
, p. 647 - 651 (2007/10/03)
The synthesis of model long-chain hydrocarbons (C13 and C 19) carrying a vinyl group and a trichloro- or a triethoxysilyl group at each end is reported. These compounds are suitable for linkage to a hydroxylated silicon surface and at the other end with vinyl group for further functionalization and multilayer formation.
Use of 1,8-bis-(dimethylamino)-naphthalene/H18F complex as new radiofluorinating agent
Pascali, Giancarlo,Kiesewetter, Dale O.,Salvadori, Piero A.,Eckelman, William C.
, p. 373 - 383 (2007/10/03)
Radiopharmaceuticals containing an 18F label are of increasing interest due to their utilization in PET imaging. However, the bottleneck in these applications is the limited methods available for introduction of this radionuclide into biologica
Synthesis of New Diols Derived from Dianhydrohexitols Ethers under Microwave-Assisted Phase Transfer Catalysis
Chatti, Saber,Bortolussi, Michel,Loupy, André
, p. 5877 - 5883 (2007/10/03)
Alkylation of mono-benzylated isosorbide and isomannide was performed under microwave assisted phase transfer catalysis (PTC). A small amount of solvent was necessary to provide good yields (90-96%) within 15 min. In order to minimize the competitive elimination, halide leaving group was changed to tosylate as competitive S(N)2-E2 processes were involved. After removal of benzyl moiety by hydrogenation, a series of new diols from dianhydrohexitols were thus prepared. (C) 2000 Elsevier Science Ltd.
Synthesis and characterization of lipophilic 1-[18F]fluoroalkyl-2- nitroimidazoles for imaging hypoxia
Yamamoto, Fumihiko,Oka, Hidenobu,Antoku, Shigetoshi,Ichiya, Yu-Ichi,Masuda, Kouji,Maeda, Minoru
, p. 590 - 597 (2007/10/03)
In order to develop new imaging markers for brain hypoxia, two lipophilic nitroimidazoles, 1-(3-fluoropropyl)-2-nitroimidazole (FPN) and 1- (8-fluorooctyl)-2-nitroimidazole (FON) were synthesized and labeled with fluorine-18. The octanol/water partition c
THA analogs useful as cholinesterase inhibitors
-
, (2008/06/13)
The present invention provides cholinesterase inhibitors of general formula (I): STR1 wherein R is H or (C 1 -C 4)alkyl, Y is a linking group and Z is an alkyl or aryl group, including heteroaryl groups, and the pharmaceutically acceptable salts thereof.
Synthesis of alkylene linked bis-THA and alkylene linked benzyl-THA as highly potent and selective inhibitors and molecular probes of acetylcholinesterase
Pang, Yuan-Ping,Hong, Feng,Quiram, Polly,Jelacic, Tanya,Brimijoin, Stephen
, p. 171 - 176 (2007/10/03)
An efficient and economical synthesis of a series of rationally designed novel 9,9′-(alkane-1,-ω-diyldiimino)-1,2,3,4-tetrahydroacridines (ω = 7-10) and a second series of new analogues, 9-(ω-phenylalkylamino)-1,2,3,4-tetrahydroacridines (ω = 4-10), is re
