214335-71-4

Basic information

• Product Name: 1-Cyclohexene-1-methanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2,6,6-trimethyl-, (4R)-
• CAS NO: 214335-71-4
• Molecular Formula: C16H32O2Si
• Molecular Weight: 284.514
• Mol File: 214335-71-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-methanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2,6,6-trimethyl-, (4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-methanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2,6,6-trimethyl-, (4R)-(214335-71-4)
• EPA Substance Registry System: 1-Cyclohexene-1-methanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2,6,6-trimethyl-, (4R)-(214335-71-4)

Safety Data

• Hazardous Substances Data: 214335-71-4(Hazardous Substances Data)

Upstream product

• 439859-82-2 4-(tert-butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enecarboxylic acid methyl ester 
• 50-00-0 formaldehyd 
• 444122-13-8 tert-butyldimethylsilyl (R)-4-iodo-3,5,5-trimethylcyclohex-3-en-1-yl ether 
• 20548-02-1 (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one 
• 130583-95-8 (4R,6R)-4-[(tert-butyldimethylsilyl)oxy]-2,2,6-trimethylcyclohexan-1-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 152187-06-9 (R)-5-(tert-butyldimethylsilyloxy)-2-[(trifluoromethanesulfonyl)oxy]-1,3,3-trimethylcyclohex-1-ene 
• 83021-07-2 (S,E)-4-[4-(tert-butyldimethylsilyloxy)-2,6,6-trimethylcyclohex-1-en-1-yl]but-3-en-2-one 

Downstream Products

• 76686-20-9 (4R)-4-hydroxy-2,6,6-trimethyl-1-cyclohexene-1-methanol 
• 171771-01-0 tert-Butyl-dimethyl-((R)-3,4,5,5-tetramethyl-cyclohex-3-enyloxy)-silane 
• 76686-24-3 (1R)-3,5,5-trimethyl-4-acetoxymethylcyclohex-3-enyl acetate 
• 214335-74-7 (1R)-3,4,5,5-tetramethylcyclohex-3-enyl acetate 
• 158694-38-3 (R)-3,4,5,5-Tetramethyl-cyclohex-3-enol 
• 1133-03-5 Loliolide 
• 8066-07-7 (1'S,2'R,4'S,2Z,4E)-(1',2'-epoxy-4'-hydroxy-2',6',6'-trimethylcyclohexyl)-3-methylpenta-2,4-dienal 
• 145165-04-4 (-)-epixanthoxin 

Relevant articles and documents

Total synthesis of naturally configured pyrrhoxanthin, a carotenoid butenolide from plankton

A carotenoid from the chemical kitchen: Two sequential Stille couplings of an unsymmetric distannane building block with a bromoolefin and a bromoalkyne terminated a highly convergent synthesis of the title compound, pyrrhoxanthin (see scheme).

The stille reaction in the synthesis of carotenoid butenolides: Synthesis of S′-epi-pridinin

(Chemical Equation Presented) A new strategy for carotenoid butenolides has been developed that is based in part in halogen-selective Stille cross-coupling of dihalogenated ylidenebutenolide segment 2 and highly functionalized alkenylstannanes.

Highly efficient stereocontrolled total synthesis of the polyfunctional carotenoid peridinin.

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