214405-70-6

Basic information

• Product Name: Toluene-4-sulfonic acid (E)-(1S,2S)-1-[(3R,4R)-7-benzyloxy-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-heptyl]-2-methoxymethoxy-dodec-3-enyl ester
• Synonyms: Toluene-4-sulfonic acid (E)-(1S,2S)-1-[(3R,4R)-7-benzyloxy-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-heptyl]-2-methoxymethoxy-dodec-3-enyl ester
• CAS NO: 214405-70-6
• Molecular Weight: 863.4
• Mol File: 214405-70-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid (E)-(1S,2S)-1-[(3R,4R)-7-benzyloxy-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-heptyl]-2-methoxymethoxy-dodec-3-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid (E)-(1S,2S)-1-[(3R,4R)-7-benzyloxy-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-heptyl]-2-methoxymethoxy-dodec-3-enyl ester(214405-70-6)
• EPA Substance Registry System: Toluene-4-sulfonic acid (E)-(1S,2S)-1-[(3R,4R)-7-benzyloxy-3,4-bis-(tert-butyl-dimethyl-silanyloxy)-heptyl]-2-methoxymethoxy-dodec-3-enyl ester(214405-70-6)

Safety Data

• Hazardous Substances Data: 214405-70-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 214405-69-3 (9E)-(11S,12S,15R,16R)-19-benzyloxy-15,16-di[(tert-butyldimethylsilyl)oxy]-11-(methoxymethoxy)-9-nonadecen-12-ol 
• 204572-66-7 (4R,5R)-8-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-octanal 

Downstream Products

• 214405-84-2 (12R,15R,16S,19R)-12-(tert-Butyl-dimethyl-silanyloxy)-16,19-bis-methoxymethoxy-19-[(2R,5R)-5-((S)-1-methoxymethoxy-undecyl)-tetrahydro-furan-2-yl]-15-(toluene-4-sulfonyloxy)-nonadecanoic acid ethyl ester 
• 214405-82-0 ethyl (12R,15R,16S,19R,20R,23R,24S)-15-[(benzyloxymeth)oxy]-12-[(tert-butyldimethylsilyl)oxy]-16,19,24-tri(methoxymethoxy)-20,23-oxido-tetratriacontanoate 
• 214405-81-9 ethyl (12R,15R,16S,19R,20R,23R,24S)-15-[(benzyloxymeth)oxy]-12-hydroxy-16,19,24-tri(methoxymethoxy)-20,23-oxidotetratriacontanoate 
• 214405-77-3 (2E)-(4R,5S,8R,9R,12R,13S)-4-[(benzyloxymeth)oxy]-1-[(tert-butyldimethylsilyl)oxy]-5,8,13-tri(methoxymethoxy)-9,12-oxido-2-tricosene 
• 214405-78-4 (4R,5S,8R,9R,12R,13S)-4-[(benzyloxymeth)oxy]-1-[(tert-butyldimethylsilyl)oxy]-5,8,13-tri(methoxymethoxy)-9,12-oxidotricosane 
• 214405-76-2 (2E)-(4R,5S,8R,9R,12R,13S)-4-[(benzyloxymeth)oxy]-1-[(tert-butyldimethylsilyl)oxy]-8,13-di(methoxymethoxy)-9,12-oxido-2-tricosen-5-ol 
• 214405-79-5 (4R,5S,8R,9R,12R,13S)-4-[(benzyloxymeth)oxy]-5,8,13-tri(methoxymethoxy)-9,12-oxido-1-tricosanol 
• 214405-80-8 (4R,5S,8R,9R,12R,13S)-4-[(benzyloxymeth)oxy]-5,8,13-tri(methoxymethoxy)-9,12-oxidotricosanal 
• 214405-72-8 (2R,5R)-2-((R)-4-Benzyloxy-1-methoxymethoxy-butyl)-5-((E)-(S)-1-methoxymethoxy-undec-2-enyl)-tetrahydro-furan 
• 214405-71-7 (9E)-(11S,12R,15R,16R)-19-benzyloxy-11-(methoxymethoxy)-12,15-oxido-9-nonadecen-16-ol 

Relevant articles and documents

Total synthesis of the nonadjacent bis-tetrahydrofuran Annonaceous acetogenin squamostatin-D

A total synthesis of the Annonaceous acetogenin squamostatin-D is described. Key adjacent stereocenters were introduced through enantioselective addition of chiral oxygenated allylic tin and indium reagents to aldehyde subunits. The isolated stereocenter at C12 was constructed through addition of a functionalized organozinc reagent to an aldehyde subunit in the presence of a chiral bis-sulfonamide-titanium catalyst.