214417-36-4

Upstream product

• 5781-53-3 monomethyl oxalyl chloride 
• 20549-72-8 4-phenoxybutyl iodide 
• 69687-95-2 ethyl 5-(phenoxy)pentanoate 
• 854879-95-1 2-(3-phenoxy-propyl)-acetoacetic acid ethyl ester 
• 588-63-6 3-phenoxypropyl bromide 
• 7170-40-3 5-phenoxyvaleric acid 

Downstream Products

• 502645-82-1 1-[4-(6-Ethyl-thieno[2,3-d]pyrimidin-4-yl)-piperazin-1-yl]-5-phenoxy-pentan-1-one 
• 214417-20-6 4-Chloro-2-(4-phenoxy-butyl)-thieno[3,2-d]pyrimidine 
• 214417-10-4 2-(4-Phenoxy-butyl)-3H-thieno[3,2-d]pyrimidin-4-one 

Relevant academic research and scientific papers

Free radical-mediated carboxylation by radical reaction of alkyl iodides with methyl oxalyl chloride

Free radical-mediated carboxylation is achieved by treatment of alkyl iodides with methyl oxalyl chloride and bis(tributyltin) in benzene at 350 nm to afford the corresponding acid chlorides as a major product along with a small amount of the methyl esters.