214552-42-8

Basic information

• Product Name: 2-(tert-Butyl-dimethyl-silanyl)-6-(2-hydroxy-2-phenyl-ethyl)-4-methoxy-benzo[b]thiophene-5-carboxylic acid diethylamide
• CAS NO: 214552-42-8
• Molecular Weight: 497.774
• Mol File: 214552-42-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(tert-Butyl-dimethyl-silanyl)-6-(2-hydroxy-2-phenyl-ethyl)-4-methoxy-benzo[b]thiophene-5-carboxylic acid diethylamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(tert-Butyl-dimethyl-silanyl)-6-(2-hydroxy-2-phenyl-ethyl)-4-methoxy-benzo[b]thiophene-5-carboxylic acid diethylamide(214552-42-8)
• EPA Substance Registry System: 2-(tert-Butyl-dimethyl-silanyl)-6-(2-hydroxy-2-phenyl-ethyl)-4-methoxy-benzo[b]thiophene-5-carboxylic acid diethylamide(214552-42-8)

Safety Data

• Hazardous Substances Data: 214552-42-8(Hazardous Substances Data)

Upstream product

• 88-10-8 N,N-diethylcarbamyl chloride 
• 214552-31-5 N,N-diethyl-4-methoxy-2-tert-butyldimethylsilylbenzo[b]thiophene-5-carboxamide 
• 3781-90-6 4-methoxybenzo[b]thiophene 
• 3610-02-4 4-hydroxybenzothiophene 
• 100-52-7 benzaldehyde 
• 214552-41-7 2-(tert-Butyl-dimethyl-silanyl)-4-methoxy-6-methyl-benzo[b]thiophene-5-carboxylic acid diethylamide 
• 214552-39-3 N,N-diethyl-4-methoxybenzo[b]thiophene-5-carboxamide 
• 214552-25-7 N,N-diethyl-4-carbamoyloxybenzo[b]thiophene 
• 214552-27-9 tert-Butyl-(4-methoxy-benzo[b]thiophen-2-yl)-dimethyl-silane 
• 214552-38-2 4-Hydroxy-benzo[b]thiophene-5-carboxylic acid diethylamide 

Relevant articles and documents

Studies in sulfur heterocycles. Part 14. Application of heteroatom directed ortho-metallation in functionalisation of benzo[b]thiophene derivatives

Heteroatom directed ortho-metallation of 2-tert-butyldimethylsilyl-4-methoxybenzo[b]thiophene and 2-tert-butyldimethylsilyl-4-carbamoyloxybenzo[b]thiophene has been followed by quenching with electrophiles. Anionic ortho-Fries rearrangement has been carri