214621-93-9Relevant academic research and scientific papers
Indium as a radical initiator in aqueous media: Intermolecular alkyl radical addition to C=N and C=C bond
Miyabe, Hideto,Ueda, Masafumi,Nishimura, Azusa,Naito, Takeaki
, p. 4227 - 4235 (2007/10/03)
The carbon-carbon bond-forming method in aqueous media was investigated by using indium as a single-electron transfer radical initiator. The indium-mediated intermolecular alkyl radical addition to imine derivatives and electron-deficient C=C bond proceeded effectively.
Indium-mediated intermolecular alkyl radical addition to electron-deficient C=N bond and C=C bond in water
Miyabe, Hideto,Ueda, Masafumi,Nishimura, Azusa,Naito, Takeaki
, p. 131 - 133 (2007/10/03)
(matrix presented) The intermolecular alkyl radical addition to imine derivatives was studied in aqueous media by using indium as a single-electron-transfer radical initiator. The one-pot reaction based on radical addition to glyoxylic hydrazone provided a convenient method for preparing the α-amino acids. The indium-mediated radical addition to an electron-deficient C=C bond also proceeded effectively to provide the new carbon-carbon bond-forming method in aqueous media.
Intermolecular alkyl radical addition to the carbon-nitrogen double bond of oxime ethers and hydrazones
Miyabe, Hideto,Shibata, Ryouhei,Sangawa, Masato,Ushiro, Chikage,Naito, Takeaki
, p. 11431 - 11444 (2007/10/03)
Intermolecular carbon radical addition to the carbon-nitrogen double bond of oxime ethers and hydrazones was studied. The reaction of unactivated aldoxime ethers proceeded smoothly in the presence of BF3·OEt2 to give the alkylated products in high yields via the free radical-mediated carbon- carbon bond-forming process.
