214892-25-8Relevant academic research and scientific papers
From p-benzoquinone to cyclohexane chirons: First asymmetric synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide
Busque, Felix,Canto, Mariona,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 2021 - 2032 (2007/10/03)
Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes.
Synthesis of agarofuran antifeedants. Part 6: Enantioselective synthesis of a key decalinic intermediate
Boyer, Francois-Didier,Prange, Thierry,Ducrot, Paul-Henri
, p. 1153 - 1159 (2007/10/03)
The asymmetric synthesis of a template decalin precursor in the synthesis of polyhydroxylated agarofuran sesquiterpenes is described via a Lewis acid catalysed addition of furan to an activated cyclohexenone directed by an adjacent chiral ketal moiety.
From p-benzoquinone to useful chiral cyclohexane building blocks
Busque, Felix,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 3077 - 3080 (2007/10/03)
A straightforward and efficient access to 12 new cyclohexane chirons from an easily available enantiopure monoketal of p-benzoquinone is described. These chirons possess a variety of functional groups which render them useful for further synthetic elabora
