214892-25-8Relevant academic research and scientific papers
Synthesis of agarofuran antifeedants. Part 6: Enantioselective synthesis of a key decalinic intermediate
Boyer, Francois-Didier,Prange, Thierry,Ducrot, Paul-Henri
, p. 1153 - 1159 (2007/10/03)
The asymmetric synthesis of a template decalin precursor in the synthesis of polyhydroxylated agarofuran sesquiterpenes is described via a Lewis acid catalysed addition of furan to an activated cyclohexenone directed by an adjacent chiral ketal moiety.
From p-benzoquinone to cyclohexane chirons: First asymmetric synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide
Busque, Felix,Canto, Mariona,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 2021 - 2032 (2007/10/03)
Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes.
From p-benzoquinone to useful chiral cyclohexane building blocks
Busque, Felix,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 3077 - 3080 (2007/10/03)
A straightforward and efficient access to 12 new cyclohexane chirons from an easily available enantiopure monoketal of p-benzoquinone is described. These chirons possess a variety of functional groups which render them useful for further synthetic elabora
