214899-59-9

Upstream product

• 17590-58-8 2-benzylidene-1,3-dithiane 
• 100-52-7 benzaldehyde 
• 214899-24-8 (+)-diethyl [(1R,3R)-1,3-dioxo-1,3-dithian-2-yl]phosphonate 

Downstream Products

• 866016-88-8 (3R,1'R,3'R)-3-(1,3-dioxo-1λ⁴,3λ⁴-[1,3]dithian-2-yl)-1,3-diphenyl-propan-1-one 
• 215055-26-8 (2R,4R,8R)-2-Phenyl-1-oxa-4,8-dithia-spiro[2.5]octane 4,8-dioxide 
• 866016-94-6 (R)-3-([1,3]dithian-2-yl)-1,3-diphenylpropan-1-one 

Relevant academic research and scientific papers

Enolate addition to a 2-alkylidene[1,3]dithiane-derived bissulfoxide. A new a2-acceptor

(Chemical Equation Presented) Reaction of enolates derived from esters and ketones to an easily prepared alkylidene[1,3]dithiane-1,3-dioxide afforded the respective adducts with good yields and selectivities generally exceeding 85:15. The base used for en

Highly enantioselective oxidations of ketene dithioacetals leading to trans bis-sulfoxides

Ketene dithioacetals undergo a Sharpless-type asymmetric oxidation using (+)-DET, Ti(OZPr)4, and cumene hydroperoxide to give the trans bis-sulfoxides 4a-f with essentially complete control of enantioselectivity and dia-stereoselectivity. The high enantio

Diastereomerically pure spirocyclic bis-sulfinyl oxiranes and their application to the asymmetric synthesis of α-amino amides

Optically pure spirocyclic bis-sulfinyl oxiranes 4 have been prepared and converted in a single step into α-amino amides.

Stereoselective epoxidation of bis-sulfinyl alkenes and application to the asymmetric synthesis of α-substituted carboxylic acids

Ketene thioacetals 3 can be easily prepared in optically pure form and react diastereoselectively with metal peroxides. The resulting bis-sulfinyl oxiranes can be converted in a single step to α-substituted acids.