2151-49-7Relevant academic research and scientific papers
Interaction of bis(diisopropylamino)carbene with aroylimines activated by trifluoromethyl groups
Poliakov, Dmytro,Rogalyov, Alexey,Shevchenko, Igor
experimental part, p. 5805 - 5809 (2009/06/08)
Bis(diisopropylamino)carbene deoxygenates the carbonyl group of aroylimines Ar-C(O)-N=C(CF3)2 to form alkenes, which formally result from the coupling of two carbenes, [Ar-C(:)-N=C(CF3)2] and [(iPr2N)
Kinetic stability of novel nitrile ylides
Hegarty, Anthony F.,Eustace, Stephen J.,Tynan, Nuala M.,Pham-Tran, Nguyen-Nguyen,Nguyen, Minh Tho
, p. 1239 - 1246 (2007/10/03)
A series of relatively stable novel trifluoromethyl substituted nitrile ylides have been generated by base promoted elimination of hydrogen chloride from the corresponding imidoyl chlorides in acetonitrile and aqueous dioxane solution at 25 °C. The format
