21510-59-8Relevant academic research and scientific papers
Trichloromethylphosphonic Acid Dihydrazide and 3,6-Bis(trichloromethyl)-3,6-dioxo-1,2,4,5-tetraaza-3,6-diphosphacyclohexane
Engelhardt, Udo,Kirner, Ingeborg
, p. 190 - 194 (2007/10/02)
The title compounds are prepared from trichloromethylphosphonic acid dichloride and excess hydrazine hydrate, and from the dihydrazide and the dichloride in the presence of triethylamine, resp.They are characterized by elemental analysis, mass spectra, 1H and 31P NMR spectra, IR and Raman data.Thin layer chromatographic experiments show that in the raw material of the ring compound two isomers (probably cis- and trans-) are present, whereas in the recrystallized product only one isomer can be detected.Attempts of a preparative separation of isomers were unsuccessfull so far due to very low concentrations of the product with the slightly higher Rf.Single crystals of the isolated ring compound decompose on irradiation with X-rays. - Key words: Inorganic Phosphorus Hydrazine Heterocycle
POLYHALOGENIERTE ETHANE IN DER KINNEAR-PERREN-REAKTION
Bauer, Gert,Haegele, Gerhard,Sartori, Peter
, p. 95 - 98 (2007/10/02)
Fluorinated ethanes (Refrigerants) were caused to react with AlCl3 and PCl3 of CH3PCl2 resp.Complete defluorination led to polychlorinated phosphonicdichlorides and phosphinicchlorides.Reactions with AlBr3 and PB3 produced halogenated ethyldibromophosphines.
