215313-76-1Relevant articles and documents
Light-Mediated Cross-Coupling of Anomeric Trifluoroborates
Miller, Eric M.,Walczak, Maciej A.
supporting information, p. 4289 - 4293 (2021/06/28)
Stereoselective reactions at the anomeric carbon constitute the cornerstone of preparative carbohydrate chemistry. Here, we report stereoselective C-arylation and etherification reactions of anomeric trifluoroborates derived from BMIDA esters. These react
Highly Stereospecific Cross-Coupling Reactions of Anomeric Stannanes for the Synthesis of C-Aryl Glycosides
Zhu, Feng,Rourke, Michael J.,Yang, Tianyi,Rodriguez, Jacob,Walczak, Maciej A.
supporting information, p. 12049 - 12052 (2016/10/03)
We demonstrate that configurationally stable anomeric stannanes undergo a stereospecific cross-coupling reaction with aromatic halides in the presence of a palladium catalyst with exceptionally high levels of stereocontrol. In addition to a broad substrat