162060-53-9

Upstream product

• 80040-79-5 3,4,6-tri-O-benzyl-D-galactal 
• 108-94-1 cyclohexanone 
• 112289-38-0 1,2-anhydro-3,4,6-tri-O-benzyl-D-galactopyranose 
• 78-84-2 isobutyraldehyde 
• 67-64-1 acetone 
• 20672-66-6 3,4,5-tri-O-benzyl-D-galactopyranose 
• 215313-76-1 3,4,6-tri-O-benzyl-α-D-galactopyranosyl chloride 
• 162060-52-8 ((2S,3R,4S,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-phenylselanyl-tetrahydro-pyran-3-yloxy)-((2S,4S,5R,6S)-4,5-bis-benzyloxy-6-methoxy-3-methylene-tetrahydro-pyran-2-ylmethoxy)-dimethyl-silane 

Downstream Products

• 3971-48-0 1,5-anhydro-D-galactitol 

Relevant academic research and scientific papers

Samarium diiodide-mediated reductive coupling of epoxides and carbonyl compounds: A stereocontrolled synthesis of C-glycosides from 1,2-anhydro sugars

Sugar mimics: 1,2-anhydro sugars can be cross-coupled with aldehydes and ketones under very mild conditions and using a wide range of protecting groups to give C-glycosides in good yield in a radical reaction mediated by SmI2 (see scheme; A = n

C-glycosides: A stereoselective synthesis of α- and β-C-galactosides with glycosyl dianions

α- or β-C-galactosides can be obtained from the configurationally stable anomeric glycosyl dianions which are prepared by transmetallation of a tin compound or by reductive lithiation of a chloride. Different electrophiles react selectively at the anomeric center.

The Use Of Selenophenyl Galactopyranosides for the Synthesis of α- and β-(1->4)-C-Disaccharides

Methyl α-C-lactoside 4)-α-D-Glcp-OMe> and its α anomer were expeditiously synthesized by radical coupling of various selenophenyl galactopyranosides onto methyl 2,3-di-O-benzyl-4-deoxy-4-C-methylene-α-D-xylo-hexopyranoside, which are tempor