215436-89-8Relevant academic research and scientific papers
Binuclear diorganophosphinothioformamido complexes of gold(I): Synthesis and crystal structure of [Au(Ph2PC(S)NPh)]2 and related systems
Clajus, Detlev,Kramolowsky, Reinhard,Siasios, George,Tiekink, Edward R.T.
, p. 64 - 69 (1998)
Binuclear gold compounds, [Au(R2PC(S) NR′)]2, were characterized from the reactions of HAuCl4 or Ph3PAuCl with R2PC(S)N(H)R′. The complexes feature bidentate bridging ligands that link two gold centres leading to eight-membered metallacycles and linear S-Au-P coordination geometries. In the case of [Au(Ph2PC(S)NPh)]2, crystal structure analysis shows the presence of two conformations in the one lattice, i.e. an extended chair and a twisted conformation.
