Inorganica Chimica Acta p. 64 - 69 (1998)
Update date:2022-08-03
Topics:
Clajus, Detlev
Kramolowsky, Reinhard
Siasios, George
Tiekink, Edward R.T.
Binuclear gold compounds, [Au(R2PC(S) NR′)]2, were characterized from the reactions of HAuCl4 or Ph3PAuCl with R2PC(S)N(H)R′. The complexes feature bidentate bridging ligands that link two gold centres leading to eight-membered metallacycles and linear S-Au-P coordination geometries. In the case of [Au(Ph2PC(S)NPh)]2, crystal structure analysis shows the presence of two conformations in the one lattice, i.e. an extended chair and a twisted conformation.
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