215594-97-1

Basic information

• Product Name: [Ni(CH₃)2(NC₅H₄CHNC₆H₃(CH(CH₃)2)2)]
• CAS NO: 215594-97-1
• Molecular Weight: 355.146
• Mol File: 215594-97-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Ni(CH₃)2(NC₅H₄CHNC₆H₃(CH(CH₃)2)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ni(CH₃)2(NC₅H₄CHNC₆H₃(CH(CH₃)2)2)](215594-97-1)
• EPA Substance Registry System: [Ni(CH₃)2(NC₅H₄CHNC₆H₃(CH(CH₃)2)2)](215594-97-1)

Safety Data

• Hazardous Substances Data: 215594-97-1(Hazardous Substances Data)

Upstream product

• 632326-69-3 bis(pyridine)dimethylnickel(II) 
• 149810-35-5 2-(((2,6-diisopropylphenyl)imino)methyl)pyridine 
• 215594-94-8 2-((2,6-diisopropylphenylimino)methyl)pyridine nickel dibromide 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 548456-85-5 [2-((2,6-diisopropylphenylimino)methyl)pyridine nickel methyl diethyletherate] (tetrakis[3,5-bis(trifluoromethyl)phenyl]borate) 

Relevant articles and documents

Synthesis of dialkyl, diaryl and metallacyclic complexes of Ni and Pd containing pyridine, α-diimines and other nitrogen ligands. Crystal structures of the complexes cis-NiR2 py2 (R = benzyl, mesityl)

The alkylation of NiCl2py4 or PdCl2 py2 with organomagnesium or organolithium reagents affords dialkyl complexes cis-MR2py2 (R=Me, CH2 SiMe3, CH2Ph, CH2CMe2 Ph, 2,4,6-C6H2Me3). The methyl and trimethylsilyl derivatives undergo ligand exchange reactions with chelating nitrogen ligands (α-diimines or 2-imidoylpyridines), yielding the corresponding dialkyl derivatives in good to excellent yields. A catalytic amount of PMe3 induces the transformation of the nickel complex Ni(CH2CMe2Ph)2 py2 into the metallacyclic derivative NiCH2CMe2-o-C6H4(py) 2.The latter, and the related palladacycle Pd(CH2CMe2-o-C6H4) (cod), also undergo facile ligand exchange reactions.