215609-09-9

Basic information

• Product Name: 4-Methoxy-benzoic acid 1,6-dimethyl-2-oxo-1,2-dihydro-pyridin-4-yl ester
• Synonyms: 4-Methoxy-benzoic acid 1,6-dimethyl-2-oxo-1,2-dihydro-pyridin-4-yl ester
• CAS NO: 215609-09-9
• Molecular Weight: 273.288
• Mol File: 215609-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Methoxy-benzoic acid 1,6-dimethyl-2-oxo-1,2-dihydro-pyridin-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methoxy-benzoic acid 1,6-dimethyl-2-oxo-1,2-dihydro-pyridin-4-yl ester(215609-09-9)
• EPA Substance Registry System: 4-Methoxy-benzoic acid 1,6-dimethyl-2-oxo-1,2-dihydro-pyridin-4-yl ester(215609-09-9)

Safety Data

• Hazardous Substances Data: 215609-09-9(Hazardous Substances Data)

Upstream product

• 6052-75-1 4-hydroxy-1,6-dimethylpyridin-2(1H)-one 
• 100-07-2 4-methoxy-benzoyl chloride 

Downstream Products

• 215609-20-4 4-Hydroxy-3-(4-methoxy-benzoyl)-1,6-dimethyl-1H-pyridin-2-one 

Relevant articles and documents

Synthesis of tricarbonylmethane derivatives of pyridines, pyrimidines, pyridazines, and pyrazoles by anionic ortho-Fries rearrangement

Heterocyclic 1,3-dicarbonyl systems, such as 4-hydroxy-2-pyridones, 6-hydroxy-4-pyrimidones, and 5-hydroxy-1-phenyl-3-pyrazolones, are converted with a number of aromatic acid chlorides to their enol esters which can be rearranged in the presence of KCN, triethylamine, and 18-crown-6 as catalyst to yield heterocyclic aryl ketones. This reaction can also be performed in a one-pot procedure without isolation of the esters. Aryl esters of 5-hydroxy-3-pyridazinone can be prepared in the same manner, but not be rearranged.