215794-89-1

Basic information

• Product Name: pyrimidin-2-yl 2,3,4,-tri-O-benzyl-1-thio-α-L-rhamnopyranoside
• Synonyms: pyrimidin-2-yl 2,3,4,-tri-O-benzyl-1-thio-α-L-rhamnopyranoside
• CAS NO: 215794-89-1
• Molecular Weight: 528.672
• Mol File: 215794-89-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pyrimidin-2-yl 2,3,4,-tri-O-benzyl-1-thio-α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: pyrimidin-2-yl 2,3,4,-tri-O-benzyl-1-thio-α-L-rhamnopyranoside(215794-89-1)
• EPA Substance Registry System: pyrimidin-2-yl 2,3,4,-tri-O-benzyl-1-thio-α-L-rhamnopyranoside(215794-89-1)

Safety Data

• Hazardous Substances Data: 215794-89-1(Hazardous Substances Data)

Upstream product

• 215794-84-6 pyrimidin-2-yl 2,3,4,-tri-O-acetyl-1-thio-α-L-rhamnopyranoside 
• 63753-91-3 3,4-di-O-acetyl-1,2-O-methoxyethylidene-β-L-rhamnopyranose 
• 100-39-0 benzyl bromide 

Downstream Products

• 126330-71-0 6-O-(2,3,4-tri-O-benzyl-L-rhamnopyranosyl)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 

Relevant articles and documents

Synthesis and glycosylation of pyrimidin-2-yl 1-thio-α-D-manno- and -α-L-rhamnopyranoside

Pyrimidin-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-α-D-mannopyrano side (9), pyrimidin-2-yl 2,3,4-tri-O-benzyl-α-L-rhamnopyranoside (10), pyrimidin-2-yl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside (7), and pyrimidin-2-yl 2-O-acetyl-3,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside (8) were prepared almost quantitatively from the corresponding protected 1,2-O-methoxyethylidene-β-D-manno-or-β-L-rhamnopyranose with 2-mercaptopyrimidine in the presence of mercuric bromide. Coupling reactions of the thioglycosides promoted by silver triflate with suitable glycosyl acceptors afforded 1,2-trans linked disaccharides. Copyright (C) 1998 Elsevier Science Ltd.