216235-45-9Relevant academic research and scientific papers
Synthesis of fluorine-containing cyclic α-amino acid and α-amino phosphonate derivatives by alkene metathesis
Osipov, Sergey N.,Artyushin, Oleg I.,Kolomiets, Alexey F.,Bruneau, Christian,Picquet, Michel,Dixneuf, Pierre H.
, p. 3891 - 3897 (2007/10/03)
The electrophilic imino esters XF2CC(=NPG)CO2Me and imino phosphonates CF3CC(=NPG)P(O)(OR)2 (PG = SO2Ph, Cbz, Boc) were transformed by nucleophilic and then electrophilic additions into fluorine-conta
Synthesis of fluorine-containing cyclic amino acid derivatives via ring closing olefin metathesis
Osipov, Sergey N.,Bruneau, Christian,Picquet, Michel,Kolomiets, Alexey F.,Dixneuf, Pierre H.
, p. 2053 - 2054 (2007/10/03)
New N-protected α-CF3 amino esters with two alkene chains (1,7-dienes 3 and 1,6-dienes 5) were reacted with the ring closing metathesis catalyst Ru=CHPh(Cl)2(PCy3),2 to give the α-CF3 dehydropipecolin
